Precious metal recovery is the main economic power of electronic waste (e-waste) recovery. The prediction of e-waste and its precious metal content is of great significance to the realisation of China's circular economy. In this work, the generation mechanism of e-waste is firstly deduced to determine model characteristics suitable for its prediction. Fractional derivative grey models base on a weak singular power kernel function (PFGM(q,1)) and a non-singular exponential kernel function (EFGM(q,1)) are established. Compared with the PFGM(q,1), the EFGM(q,1) has the advantages of simpler solution, lower calculation complexity and wider scope of application. Next, some data are selected to verify the validity. The EFGM(q,1) is used to predict mobile phone, laptop, desktop and television waste, and the weight of printed circuit boards (PCBs) in the waste and content of precious metals in these PCBs are calculated. Finally, the trend of e-waste and its precious metal contents are analysed and discussed based on the calculation results.
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http://dx.doi.org/10.1016/j.isatra.2020.07.023 | DOI Listing |
Dalton Trans
January 2025
National Laboratory of Solid State Microstructures and Jiangsu Provincial Key Laboratory for Nanotechnology, College of Engineering and Applied Sciences, Nanjing University, Nanjing, Jiangsu 210093, People's Republic of China.
The development of viable, stable, and highly efficient molecular water oxidation catalysts under acidic aqueous conditions (pH < 7) is challenging with Earth-abundant metals in the field of renewable energy due to their low stability and catalytic activity. The utilization of these catalysts is generally considered more cost-effective and sustainable relative to conventional catalysts relying on precious metals such as ruthenium and iridium, which exhibit outstanding activities. Herein, we discussed the effectiveness of transition metal complexes for electrocatalytic water oxidation under acidic conditions.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
School of Photovoltaic and Renewable Energy Engineering, University of New South Wales, Tyree Energy Technologies Building, 229 Anzac Parade, Kensington, NSW 2052, Australia.
An ideal water-splitting electrocatalyst is inexpensive, abundant, highly active, stable, selective, and durable. The anodic oxygen evolution reaction (OER) is the main bottleneck for H production with a complex and not fully resolved mechanism, slow kinetics, and high overpotential. Nickel oxide-based catalysts (NiO) are highly active and cheaper than precious metal catalysts.
View Article and Find Full Text PDFNat Chem
January 2025
Instituto de Investigaciones Químicas, Consejo Superior de Investigaciones Científicas and Universidad de Sevilla, Sevilla, Spain.
Open-shell systems based on first-row transition metals and their involvement in various catalytic processes are well explored. By comparison, mononuclear open-shell complexes of precious transition metals remain underdeveloped. This is particularly true for Ir complexes, as there is very limited information available regarding their application in catalysis.
View Article and Find Full Text PDFChemistry
January 2025
Tianjin University, Department of Chemistry, 92 Weijin Road, 300072, Tianjin, CHINA.
Hydrogen peroxide (H2O2) is a versatile chemical widely used in various industries. The traditional anthraquinone method for H2O2 synthesis has environmental and safety concerns due to the use of organic solvents and hazardous by-products. The direct synthesis of H2O2 from H2 and O2 poses risks of flammability and explosion.
View Article and Find Full Text PDFDalton Trans
January 2025
Department of Chemistry, Indian Institute of Technology Kharagpur-721302, WB, India.
At present, plastic pollution is a global environmental catastrophe and a major threat to mankind. Moreover, the increasing manufacture of various plastic products is causing rapid depletion of precious resources. Thus, transforming plastic waste into feedstock, which can maintain a circular economy, has emerged as a significant technique for waste management and carbon resource conservation.
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