In every parameter-estimation experiment, the final measurement or the postprocessing incurs a cost. Postselection can improve the rate of Fisher information (the average information learned about an unknown parameter from a trial) to cost. We show that this improvement stems from the negativity of a particular quasiprobability distribution, a quantum extension of a probability distribution. In a classical theory, in which all observables commute, our quasiprobability distribution is real and nonnegative. In a quantum-mechanically noncommuting theory, nonclassicality manifests in negative or nonreal quasiprobabilities. Negative quasiprobabilities enable postselected experiments to outperform optimal postselection-free experiments: postselected quantum experiments can yield anomalously large information-cost rates. This advantage, we prove, is unrealizable in any classically commuting theory. Finally, we construct a preparation-and-postselection procedure that yields an arbitrarily large Fisher information. Our results establish the nonclassicality of a metrological advantage, leveraging our quasiprobability distribution as a mathematical tool.
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http://dx.doi.org/10.1038/s41467-020-17559-w | DOI Listing |
Acc Chem Res
January 2025
Centre for Computational Chemistry, School of Chemistry, University of Bristol, Bristol BS8 1TS, United Kingdom.
ConspectusPhotochemical reactions have always been the source of a great deal of mystery. While classified as a type of chemical reaction, no doubts are allowed that the general tenets of ground-state chemistry do not directly apply to photochemical reactions. For a typical chemical reaction, understanding the critical points of the ground-state potential (free) energy surface and embedding them in a thermodynamics framework is often enough to infer reaction yields or characteristic time scales.
View Article and Find Full Text PDFEntropy (Basel)
September 2024
Hunter College and Graduate Center, City University of New York, New York, NY 10065, USA.
We consider the local value of an operator for a given position or momentum and, more generally on the value of another arbitrary observable. We develop a general approach that is based on breaking up Aψ(x) as Aψ(x)ψ(x)=Aψ(x)ψ(x)R+iAψ(x)ψ(x)I where A is the operator whose local value we seek and ψ(x) is the position wave function. We show that the real part is related to the conditional value for a given position and the imaginary part is related to the standard deviation of the conditional value.
View Article and Find Full Text PDFNat Commun
October 2024
Beijing Academy of Quantum Information Sciences, Beijing, China.
Measurement-induced state disturbance is a major challenge in obtaining quantum statistics at multiple time points. We propose a method to extract dynamic information from a quantum system at intermediate time points, namely snapshotting quantum dynamics. To this end, we apply classical post-processing after performing the ancilla-assisted measurements to cancel out the impact of the measurements at each time point.
View Article and Find Full Text PDFSci Rep
August 2024
Istituto Nazionale di Ottica del Consiglio Nazionale delle Ricerche (CNR-INO), Largo Enrico Fermi 6, 50125, Florence, Italy.
In a multi-level quantum system Fano coherences stand for the formation of quantum coherences due to the interaction with the continuum of modes characterizing an incoherent process. In this paper we propose a V-type three-level quantum system on which we certify the presence of genuinely quantum traits underlying the generation of Fano coherences. We do this by determining work conditions that allows for the loss of positivity of the Kirkwood-Dirac quasiprobability distribution of the stochastic energy changes within the discrete system.
View Article and Find Full Text PDFPhys Rev E
June 2024
Dipartimento di Fisica e Astronomia and Sezione INFN, Università di Padova, Via Marzolo 8, 35131 Padova, Italy.
Fluctuation theorems are fundamental results in nonequilibrium thermodynamics beyond the linear response regime. Among these, the paradigmatic Tasaki-Crooks fluctuation theorem relates the statistics of the works done in a forward out-of-equilibrium quantum process and in a corresponding backward one. In particular, the initial states of the two processes are thermal states and thus incoherent in the energy basis.
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