2,3,4-Tri--benzyl-D-xylopyranose was used as a starting material in the preparation of the corresponding triene, which underwent smooth cyclization to a polyhydroxylated hydrindane, as a single diastereoisomer. The analogous triene prepared from D-glucose did not undergo any cyclization even under high pressure.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7436230PMC
http://dx.doi.org/10.3390/molecules25153357DOI Listing

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