We report the synthesis and structural characterization of new neutral cyclic sp2-sp3 and sp3-sp3 diboranes from the reaction of N,N'-dicyclohexylcarbodiimide with 1,2-dichlorodiboranes(4) at room temperature. The present study is the first example of an insertion reaction of carbodiimide into diborane(4).
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| http://dx.doi.org/10.1039/d0cc03454a | DOI Listing |
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