Optical spectroscopy constitutes the historical path to accumulate basic knowledge on the atom and its structure. Former work based on fluorescence and resonance ionization spectroscopy enabled identifying optical spectral lines up to element 102, nobelium. The new challenges faced in this research field are the refractory nature of the heavier elements and the decreasing production yields. A new concept of ion-mobility-assisted laser spectroscopy is proposed to overcome the sensitivity limits of atomic structure investigations persisting in the region of the superheavy elements. The concept offers capabilities of both broadband-level searches and high-resolution hyperfine spectroscopy of synthetic elements beyond nobelium.
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http://dx.doi.org/10.1103/PhysRevLett.125.023002 | DOI Listing |
Phys Rev Lett
October 2024
Lawrence Livermore National Laboratory, Livermore, California 94550, USA.
Nature
October 2024
Institut für Physik, Johannes Gutenberg-Universität Mainz, Mainz, Germany.
The quantum-mechanical nuclear-shell structure determines the stability and limits of the existence of the heaviest nuclides with large proton numbers Z ≳ 100 (refs. ). Shell effects also affect the sizes and shapes of atomic nuclei, as shown by laser spectroscopy studies in lighter nuclides.
View Article and Find Full Text PDFFront Chem
September 2024
GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt, Germany.
Phys Chem Chem Phys
September 2024
Department of Chemistry, Oakland University, 146 Library Drive, Rochester, Michigan 48309, USA.
The fascination with superheavy elements (SHE) spans the nuclear physics, astrophysics, and theoretical chemistry communities. Extreme relativistic effects govern these elements' chemistry and challenge the traditional notion of the periodic law. The experimental quest for SHE critically depends on theoretical predictions of these elements' properties, especially chemical homology, which allows for successful prototypical experiments with more readily available lighter homologues of SHE.
View Article and Find Full Text PDFChemphyschem
August 2024
Department of Chemistry, Biology and Biotechnology, University of Perugia, via Elce di Sotto 8, 06123, Perugia, Italy.
In this work, we study the chemical bond in molecules containing heavy and super-heavy elements according to the current state-of-the-art bonding models. An Energy Decomposition Analysis in combination with Natural Orbital for Chemical Valence (EDA-NOCV) within the relativistic four-component Dirac-Kohn-Sham (DKS) framework is employed, which allows to successfully include the spin-orbit coupling (SOC) effects on the chemical bond description. Simple halogen-bonded adducts ClX⋯L (X=At, Ts; L=NH, Br, HO, CO) of astatine and tennessine have been selected to assess a trend on descending along a group, while modulating the ClX⋯L bond features through the different electronic nature of the ligand L.
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