Laser Resonance Chromatography of Superheavy Elements.

Phys Rev Lett

Science Department, Chatham University, Pittsburgh, Pennsylvania 15232, USA.

Published: July 2020

Optical spectroscopy constitutes the historical path to accumulate basic knowledge on the atom and its structure. Former work based on fluorescence and resonance ionization spectroscopy enabled identifying optical spectral lines up to element 102, nobelium. The new challenges faced in this research field are the refractory nature of the heavier elements and the decreasing production yields. A new concept of ion-mobility-assisted laser spectroscopy is proposed to overcome the sensitivity limits of atomic structure investigations persisting in the region of the superheavy elements. The concept offers capabilities of both broadband-level searches and high-resolution hyperfine spectroscopy of synthetic elements beyond nobelium.

Download full-text PDF

Source
http://dx.doi.org/10.1103/PhysRevLett.125.023002DOI Listing

Publication Analysis

Top Keywords

superheavy elements
8
laser resonance
4
resonance chromatography
4
chromatography superheavy
4
elements
4
elements optical
4
spectroscopy
4
optical spectroscopy
4
spectroscopy constitutes
4
constitutes historical
4

Similar Publications

Article Synopsis
  • - The experiment at Lawrence Berkeley National Laboratory aimed to produce a superheavy element with an atomic number of 114 or greater by bombarding an actinide target with a ^{50}Ti beam.
  • - Using the Berkeley Gas-filled Separator, researchers successfully isolated and implanted produced Livermorium (Lv) ions into a high-tech detector system, observing two decay chains linked to ^{290}Lv.
  • - The measured production cross-section of the process was 0.44 picobarns at a specific energy, marking the first published evidence of superheavy element production near the "island of stability" with this method, paving the way for future discoveries beyond element Z=118.
View Article and Find Full Text PDF

The quantum-mechanical nuclear-shell structure determines the stability and limits of the existence of the heaviest nuclides with large proton numbers Z ≳ 100 (refs. ). Shell effects also affect the sizes and shapes of atomic nuclei, as shown by laser spectroscopy studies in lighter nuclides.

View Article and Find Full Text PDF
Article Synopsis
  • Researchers conducted a study on the chemical reactivity of superheavy elements nihonium (Nh) and moscovium (Mc) using a new chromatography setup, revealing new insights into their properties.
  • The isotopes of Mc were produced at GSI Helmholtzzentrum in Germany, and their interaction with silicon oxide and gold surfaces was examined, providing the first measurements for their adsorption enthalpy.
  • The findings showed that Nh and Mc have weaker interactions with silicon oxide compared to their lighter counterparts, but display higher reactivity than neighboring elements copernicium and flerovium due to significant relativistic effects.
View Article and Find Full Text PDF

Uncovering chemical homology of superheavy elements: a close look at astatine.

Phys Chem Chem Phys

September 2024

Department of Chemistry, Oakland University, 146 Library Drive, Rochester, Michigan 48309, USA.

The fascination with superheavy elements (SHE) spans the nuclear physics, astrophysics, and theoretical chemistry communities. Extreme relativistic effects govern these elements' chemistry and challenge the traditional notion of the periodic law. The experimental quest for SHE critically depends on theoretical predictions of these elements' properties, especially chemical homology, which allows for successful prototypical experiments with more readily available lighter homologues of SHE.

View Article and Find Full Text PDF

The Chemical Bond at the Bottom of the Periodic Table: The Case of the Heavy Astatine and the Super-Heavy Tennessine.

Chemphyschem

August 2024

Department of Chemistry, Biology and Biotechnology, University of Perugia, via Elce di Sotto 8, 06123, Perugia, Italy.

In this work, we study the chemical bond in molecules containing heavy and super-heavy elements according to the current state-of-the-art bonding models. An Energy Decomposition Analysis in combination with Natural Orbital for Chemical Valence (EDA-NOCV) within the relativistic four-component Dirac-Kohn-Sham (DKS) framework is employed, which allows to successfully include the spin-orbit coupling (SOC) effects on the chemical bond description. Simple halogen-bonded adducts ClX⋯L (X=At, Ts; L=NH, Br, HO, CO) of astatine and tennessine have been selected to assess a trend on descending along a group, while modulating the ClX⋯L bond features through the different electronic nature of the ligand L.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!