AI Article Synopsis

  • A new device using Dirac semimetal films and vanadium dioxide (VO) allows for tunable functionality in terahertz (THz) applications.
  • The phase change of VO from insulator to metal enables it to switch between asymmetric transmission and dual-directional absorption of THz waves.
  • The device's performance can be adjusted by changing the Fermi energy of the semimetal films, providing innovative possibilities for multifunctional THz technology.

Article Abstract

A tunable bifunctional terahertz (THz) metamaterial device based on Dirac semimetal films (DSFs) and VO is presented. The insulator-to-metal phase transition of VO enables bifunctional asymmetric transmission and dual-directional absorption to be switched in the THz range. When VO serves as a dielectric, tunable broadband asymmetric transmission of linearly polarized THz waves can be achieved. When VO is in a metallic state, the proposed device acts as a tunable dual-directional absorber with perfect absorption in both illumination directions. In each case, the response can be tuned by varying the Fermi energy of the DSFs. This offers a new pathway for the development of tunable multifunctional THz metamaterial devices.

Download full-text PDF

Source
http://dx.doi.org/10.1364/OE.394784DOI Listing

Publication Analysis

Top Keywords

tunable bifunctional
8
bifunctional terahertz
8
metamaterial device
8
device based
8
based dirac
8
thz metamaterial
8
asymmetric transmission
8
tunable
5
terahertz metamaterial
4
dirac semimetals
4

Similar Publications

The prominence of binuclear catalysts underlines the need for the design and development of diverse bifunctional ligand frameworks that exhibit tunable electronic and structural properties. Such strategies enable metal-metal and ligand-metal cooperation towards catalytic applications, improve catalytic activity, and are essential for advancing multi-electron transfers for catalytic application. Hereby, we present the synthesis, crystal structure, and photocatalytic properties of a binuclear Ni(II) complex, [Ni2(1,10-phenanthroline)2(2-sulfidophenolate)2] (1), which crystallizes in the centrosymmetric triclinic system (P-1) showing extensive intra- and inter- non-coordinated interactions.

View Article and Find Full Text PDF

This work describes the development of the first enantioselective addition reaction between 1,3,5,7-tetramethyl-BODIPYs and isatin derivatives. The reaction utilizes bifunctional quinine/squaramide organocatalysts and affords nine novel chiral BODIPY dyes under mild conditions, with enantioselectivities reaching up to 60%. The synthesized BODIPY-oxindoles exhibit high fluorescence emissions, consistent with their parent BODIPYs, and display tunable colors.

View Article and Find Full Text PDF

Synergistic high-entropy phosphides with phosphorus vacancies as robust bifunctional catalysts for efficient water splitting.

J Colloid Interface Sci

January 2025

State Key Laboratory of Chem/Bio-Sensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082 PR China. Electronic address:

High-entropy phosphides (HEPs) have garnered increasing interest as innovative electrocatalysts for water splitting, highlighted by their distinctive catalytic activity, elemental synergy, and tunable electronic configuration. Herein, a novel electrode comprising CoNiCuZnFeP nanocubes with rich phosphorus vacancies was fabricated through coprecipitation and phosphorization two-step method. The synergistic interaction among metal elements and the modulation of the electronic configuration by phosphorus vacancies augmentation enhance the catalytic performance for both the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER).

View Article and Find Full Text PDF

Bilayer graphene ribbons (GRs) hold great promise for the fabrication of next-generation nanodevices, thanks to unparalleled electronic properties, especially the tunable bandgap in association with twist angle, ribbon width, edge structure, and interlayer coupling. A common challenge in manufacturing bilayer GRs via templated chemical vapor deposition (CVD) approach is uncontrollable dewetting of micro- and nano-scaled patterned metal substrates. Herein, a confined CVD synthetic strategy of bilayer GR arrays is proposed, by utilizing the bifunctional Ni as a buffered adhesion layer to regulate the anisotropic dewetting of metal film in the V-groove and as a carbon-dissolution regulated metal to initiate the bilayer nucleation.

View Article and Find Full Text PDF

Tunable NiSe-NiSe Heterojunction for Energy-Efficient Hydrogen Production by Coupling Urea Degradation.

Small Methods

January 2025

Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials, MOE Key Laboratory of New Processing Technology for Nonferrous Metals and Materials, School of Resources, Environment and Materials, Guangxi University, Nanning, Guangxi, 530004, China.

Urea-assisted water splitting is a promising energy-saving hydrogen (H) production technology. However, its practical application is hindered by the lack of high-performance bifunctional catalysts for urea oxidation reaction (UOR) and hydrogen evolution reaction (HER). Herein, a heterostructured catalyst comprising highly active NiSe and NiSe, along with a conductive graphene-coated nickel foam skeleton (NiSe-NiSe/GNF) is reported.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!