Hydrophilic/Aerophobic Hydrogen-Evolving Electrode: NiRu-Based Metal-Organic Framework Nanosheets In Situ Grown on Conductive Substrates.

Electrocatalytic reduction of water via hydrogen evolution reaction (HER) is considered one of the most ideal avenues to produce high-purity hydrogen (H) in large quantities, which always requires active electrocatalysts to overcome the high energy barrier. It is of significance yet challenging to design and construct effective HER electrocatalysts of an acceptable cost. In this study, a highly efficient metal-organic framework (MOF)-based electrochemical HER system based on NiRu-based binary MOF (Ru-doped Ni(BDC)TED MOF, BDC = 1,4-benzenedicarboxylic acid; TED = triethylenediamine) nanosheets grown on conductive substrates (e.g., Ni foam, carbon cloth) is fabricated by a facile solvothermal method. The resultant NiRu-MOF-based composites possess enhanced electron transport ability and water stability, accompanied by increased electrochemically active areas and hydrophilic/aerophobic properties. With these advantages, the optimized NiRu-MOF nanosheet arrays on Ni foam substrate (NiRu-MOF/NF) with a Ru/Ni molar ratio of 6/94 in the MOF structure could exhibit efficient catalytic performance for HER in alkaline conditions, requiring a small overpotential of 51 mV at -10 mA cm. This study could provide a feasible way for the design and synthesis of two-dimensional (2D) MOF-based materials with controllable interface properties for energy catalysis and beyond.