In this study, surface morphology, rheological and chemical properties were investigated of bitumen, which was modified by a composite of clay and fumed silica nanoparticles, and exposed to ultraviolet (UV) aging in laboratory. The volume fraction of the nanoparticles within the binder ranged from 1 to 3%, the temperature range considered was 30 to 70 °C. Surface morphology, rheological and chemical binder properties were analyzed using field emission scanning electron microscopy (FESEM), dynamic shear rheometer (DSR), and Fourier transform infrared (FT-IR) spectroscopy. It was found, that the bitumen modification through clay and fumed silica nanoparticles changed resulting binder properties significantly. The index of carbonyl and oxidation degree decreased, and the clay and fumed silica nanoparticles improved aging resistance to ultraviolet (UV) radiation considerably. The results indicate that the mechanical stability of the modified bitumen is very much driven by the specific concentration of clay and fumed silica nanoparticles.
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http://dx.doi.org/10.1038/s41598-020-68007-0 | DOI Listing |
ACS Omega
November 2022
Laboratory of Analytical and Molecular Chemistry (LCAM), Faculty of Sciences Ben M'Sick, Department of Chemistry, University Hassan II of Casablanca, Casablanca20000, Morocco.
Superabsorbent polymers derived from petroleum have been widely used as the primary component of high-water-absorption disposable sanitary products. However, environmental concerns as well as unstable market prices influence the quality of disposable hygiene products. The development of superabsorbent polymers from natural, non-petroleum-derived materials has become more predominant.
View Article and Find Full Text PDFSci Rep
July 2020
Braunschweig Pavement Engineering Centre, Technische Universität Braunschweig, Braunschweig, Germany.
In this study, surface morphology, rheological and chemical properties were investigated of bitumen, which was modified by a composite of clay and fumed silica nanoparticles, and exposed to ultraviolet (UV) aging in laboratory. The volume fraction of the nanoparticles within the binder ranged from 1 to 3%, the temperature range considered was 30 to 70 °C. Surface morphology, rheological and chemical binder properties were analyzed using field emission scanning electron microscopy (FESEM), dynamic shear rheometer (DSR), and Fourier transform infrared (FT-IR) spectroscopy.
View Article and Find Full Text PDFLangmuir
April 2016
Department of Chemistry, University of Hull, Hull HU6 7RX, U.K.
The preparation of powdered water-in-oil (w/o) emulsions by gentle aeration of w/o emulsions stabilized by hydrophobic fumed silica particles in the presence of oleophobic fluorinated clay particles is reported for an alkane and a triglyceride oil. The resultant powders consist of water drops dispersed in oil globules themselves dispersed in air (w/o/a). They contain ∼80 wt % of the precursor w/o emulsion and were stable to phase separation for over 1 year but release oil and water when sheared on a substrate.
View Article and Find Full Text PDFSoft Matter
January 2016
Department of Chemistry, University of Hull, Hull HU6 7RX, UK.
A brief review of the stabilisation of emulsions of two immiscible oils is given. We then describe the use of fumed silica particles coated with either hydrocarbon or fluorocarbon groups in acting as sole stabilisers of emulsions of various vegetable oils with linear silicone oils (PDMS) of different viscosity. Transitional phase inversion of emulsions, containing equal volumes of the two oils, from silicone-in-vegetable (S/V) to vegetable-in-silicone (V/S) occurs upon increasing the hydrophobicity of the particles.
View Article and Find Full Text PDFPharm Dev Technol
December 2014
Department of Polymer Engineering, School of Chemical Engineering, University of Tehran, Tehran , Iran.
The rheological and drug release behavior of biopolymer nanocomposite gels based on the cellulose derivatives, formulated as the bioadhesive drug delivery platforms, were investigated. The bioadhesive gel is composed of the microcrystalline cellulose, sodium carboxymethyl cellulose and phosphate buffered saline (pH = 7.4 at 20 °C) as the dissolution and release medium.
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