In this study, Mg and/or Al modified biochars (MABC, MBC, ABC) prepared by co-precipitation were to explore their phosphate adsorption capacity from aqueous solution and the potential for soil phosphate interception. The results revealed that MABC composites contained more functional groups than MBC and showed a higher surface area than ABC. The surface of MABC contained dispersed MgAlO, Mg(OH), AlOOH and AlO crystals that were associated with its enhanced maximum phosphate adsorption capacity (153.40 mg g). According to Langmuir model, the maximum adsorption capacity of MABC was 15.91, 1.85, and 93.54 times the capacity of MBC, ABC, and raw biochar (BC), respectively. The addition of MABC in red soil could significantly slow down the release of soil phosphorus, and MABC also had a stronger phosphate interception capacity (59.89%) than other BCs. In summary, MABC exhibits superior phosphate adsorption and interception capacity, making it ideal for treatment and prevention of phosphorus-polluted water.
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http://dx.doi.org/10.1016/j.chemosphere.2020.127469 | DOI Listing |
Environ Geochem Health
January 2025
Institute of Soil and Environmental Sciences, Pir Mehr Ali Shah Arid Agriculture University, Rawalpindi, 46300, Pakistan.
Although the use of biochar as an adsorbent for the removal of various pollutants from wastewater is well established, the use of biochar/modified biochar for the scavenging of antibiotics from aqueous media in the Fenton-like system receives less attention. The highest kasugamycin (KSM) adsorption capacity (5.0 mg g) was obtained from the pristine biochar at the lowest initial pH of 3 in Fenton-like system.
View Article and Find Full Text PDFHeliyon
January 2025
Department of Nutrition and Dietetics, Faculty of Health Science, Mardin Artuklu University, Mardin, Turkey.
In the current research mushroom/bentonite clay (RDBNC) as a low-cost bionanosorbent was investigated for adsorption of methylene blue (MB) and malachite green (MG) dye from contaminated water. The bionanosorbent was characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD), Scanning electron microscopy (FESEM), Thermal Gravimetric Analysis (TGA), and Zeta-potential techniques. Adsorption experiments of RDBNC for MB, MG dyes following Freundlich isotherm and pseudo second order kinetic models.
View Article and Find Full Text PDFFood Chem X
January 2025
Flavors and Fragrance Engineering & Technology Research Center of Henan Province, College of Tobacco Science, Henan Agricultural University, Zhengzhou 450002, China.
The stabilities and sustained-release properties of citral are significant for foods. Herein, bacterial cellulose (BC) was innovatively reported for adsorption and sustained-release of citral via gas-phase adsorption technique, and the adsorption mechanism was disclosed. BC was prepared from tobacco stem waste extract (TSWE), and better adsorption capacity (124.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Tsinghua University, Institute of Nuclear and New Energy Technology, Room A320, Nengke Building, Qinghua Yuan No.1, Beijing, CHINA.
Exploiting supramolecular secondary building units (SSBUs) for developing porous crystalline materials represents an exciting breakthrough that extends the boundaries of reticular chemistry. However, shaping polynuclear clusters sustained by non-covalent interactions for the assembly of hydrogen-bonded frameworks remains a critical challenge. This study presents a novel strategy to stabilize SSBUs by tuning the π-stacking geometry of conjugated building blocks, facilitating the creation of hydrogen-bonded frameworks with tailored architectures for demanding gas separation.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
Formaldehyde (HCHO) has become a significant indoor air pollutant, arising from the widespread use of decorative and construction materials. Adsorption is the most convenient method for HCHO removal. However, the current adsorption is limited by the current low adsorption capacity and desorption.
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