AI Article Synopsis
- Derivatives of the cationic compound ITrop are created through hydride abstraction from cycloheptatriene-related compounds.
- ITrop, a cationic version of benzimidazolylidenes, shows a significantly reduced ability to donate σ-electrons while having a strong capacity to accept π-electrons.
- Various spectroscopic, structural, and theoretical analyses support these findings about ITrop's electronic properties.
Article Abstract
Derivatives of the cationic tropylium annulated imidazolylidene ITrop are obtained by hydride abstraction from related cycloheptatriene compounds. Spectroscopic, structural and theoretical data indicate that, as a cationic relative of benzimidazolylidenes, ITrop has highly reduced σ-donor and strong π-acceptor character.
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| http://dx.doi.org/10.1039/d0cc04482b | DOI Listing |
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