Ensuring nuclear safety has become of great significance as nuclear power is playing an increasingly important role in supplying worldwide electricity. β-ray monitoring is a crucial method, but commercial organic scintillators for β-ray detection suffer from high temperature failure and irradiation damage. Here, we report a type of β-ray scintillator with good thermotolerance and irradiation hardness based on a two-dimensional halide perovskite. Comprehensive composition engineering and doping are carried out with the rationale elaborated. Consequently, effective β-ray scintillation is obtained, the scintillator shows satisfactory thermal quenching and high decomposition temperature, no functionality decay or hysteresis is observed after an accumulated radiation dose of 10 kGy (dose rate 0.67 kGy h). Besides, the two-dimensional halide perovskite β-ray scintillator also overcomes the notorious intrinsic water instability, and benefits from low-cost aqueous synthesis along with superior waterproofness, thus paving the way towards practical application.
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http://dx.doi.org/10.1038/s41467-020-17114-7 | DOI Listing |
J Chem Inf Model
January 2025
Division of Physics & Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore.
With remarkable stability and exceptional optoelectronic properties, two-dimensional (2D) halide layered perovskites hold immense promise for revolutionizing photovoltaic technology. Effective data representations are key to the success of all learning models. Currently, the lack of comprehensive and accurate material representations has hindered AI-based design and discovery of 2D perovskites, limiting their potential for advanced photovoltaic applications.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Chemistry, Sogang University, Seoul 04107, Republic of Korea.
Two-dimensional (2D) organic-inorganic hybrid metal halides (OIMHs), characterized by noncentrosymmetric structures arising from the incorporation of chiral organic molecules that break inversion symmetry, have attracted significant attention. Particularly, chiral-polar 2D OIMHs offer a unique platform for multifunctional applications, as the coexistence of chirality and polarity enables the simultaneous manifestation of distinct properties such as nonlinear optical (NLO) effects, circular dichroism (CD), and ferroelectricity. In this study, we report the first synthesis of hafnium (Hf)-based chiral 2D OIMHs, achieved through the strategic incorporation of -substituents on the benzene ring of chiral organic components.
View Article and Find Full Text PDFInorg Chem
January 2025
School of Chemistry and Chemical Engineering, Nanchang University, Nanchang 330031, P. R. China.
Organic-inorganic hybrid lead halides have been extensively studied due to their outstanding physical properties and diverse compositional elements. However, environmentally benign tin-based hybrids with remarkable flexibility in bandgap engineering have been less investigated. Herein, we report the successful design and synthesis of three tin-based organic-inorganic hybrid compounds through precise molecular modification: [Me(i-Pr)N][SnBr] (), [MeCHCl(i-Pr)N][SnBr] (), and [MeCHBr(i-Pr-Br)N][SnBr] ().
View Article and Find Full Text PDFACS Nano
December 2024
Department of Materials Science and Engineering, Yonsei University, Seoul 03722, Republic of Korea.
Physical unclonable functions (PUFs), often referred to as digital fingerprints, are emerging as critical elements in enhancing hardware security and encryption. While significant progress has been made in developing optical and memory-based PUFs, integrating reconfigurability with sensitivity to circularly polarized light (CPL) remains largely unexplored. Here, we present a chiroptical synaptic memristor (CSM) as a reconfigurable PUF, leveraging a two-dimensional organic-inorganic halide chiral perovskite.
View Article and Find Full Text PDFACS Nano
December 2024
Interuniversity Microelectronics Center (imec), Leuven 3001, Belgium.
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