In this paper, we analyze the dynamics and formation mechanisms of bound states (BSs) of light bullets in the output of a laser coupled to a distant saturable absorber. First, we approximate the full three-dimensional set of Haus master equations by a reduced equation governing the dynamics of the transverse profile. This effective theory allows us to perform a detailed multiparameter bifurcation study and to identify the different mechanisms of instability of BSs. In addition, our analysis reveals a non-intuitive dependence of the stability region as a function of the linewidth enhancement factors and the field diffusion. Our results are confirmed by direct numerical simulations of the full system.
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http://dx.doi.org/10.1063/5.0003227 | DOI Listing |
ACS Nano
January 2025
IBM Almaden Research Center, 650 Harry Road, San Jose, California 95120, United States.
Lanthanide atoms show long magnetic lifetimes because of their strongly localized 4 electrons, but electrical control of their spins has been difficult because of their closed valence shell configurations. We achieved electron spin resonance of individual lanthanide atoms using a scanning tunneling microscope to probe the atoms bound to a protective insulating film. The atoms on this surface formed a singly charged cation state having an unpaired 6 electron, enabling tunnel current to access their 4 electrons.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Harvard University, Rowland Institute at Harvard, 02138, Cambridge, UNITED STATES OF AMERICA.
The dynamic response of heterogeneous catalytic materials to their environment opens a wide variety of possible surface states which may have increased catalytic activity. In this work, we find that it is possible to generate a surface state with increased catalytic activity over metallic 2nm Pt nanoparticles by performing a thermal treatment of the CO*-covered Pt catalyst. This state is characterised by its ability to oxidise CO to CO2 at room temperature.
View Article and Find Full Text PDFInorg Chem
January 2025
University of Göttingen, Institute of Inorganic Chemistry, Tammannstrasse 4, D-37077 Göttingen, Germany.
Alkyl nickel intermediates relevant to catalytic processes often feature agostic stabilization, but relatively little is known about the situation in oligonickel systems. The dinickel(I) complex K[LNi], which is based on a compartmental pyrazolato-bridged ligand L with two β-diketiminato chelate arms, or its masked version, the dihydride complex [KL(Ni-H)] that readily releases H, oxidatively add methyl tosylate to give diamagnetic [LNi(CH)] () with (Ni···Ni) ≈ 3.7 Å.
View Article and Find Full Text PDFInorg Chem
January 2025
State Key Laboratory of Molecular & Process Engineering, SINOPEC Research Institute of Petroleum Processing, Beijing 100083, China.
The ZSM-5 zeolite is the key active component in high-severity fluid catalytic cracking (FCC) catalysts and is routinely activated by phosphorus compounds in industrial production. To date, however, the detailed structure and function of the introduced phosphorus still remain ambiguous, which hampers the rational design of highly efficient catalysts. In this work, using advanced solid-state NMR techniques, we have quantitatively identified a total of seven types of P-containing complexes in P-modified ZSM-5 zeolite and clearly revealed their structure, location, and catalytic role.
View Article and Find Full Text PDFActa Pharm Sin B
December 2024
State Key Laboratory of Cellular Stress Biology and Fujian Provincial Key Laboratory of Innovative Drug Target Research, School of Pharmaceutical Science, Xiamen University, Xiamen 361102, China.
The orphan nuclear receptor Nur77 is emerging as an attractive target for cancer therapy, and activating Nur77's non-genotypic anticancer function has demonstrated strong therapeutic potential. However, few Nur77 site B ligands have been identified as excellent anticancer compounds. There are no co-crystal structures of effective anticancer agents at Nur77 site B, which greatly limits the development of novel Nur77 site B ligands.
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