Direct recovery of interfacial topography from coherent X-ray reflectivity: model calculations for a 1D interface.

Acta Crystallogr A Found Adv

Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Lemont, IL 60439, USA.

Published: July 2020

The use of coherent X-ray reflectivity to recover interfacial topography is described using model calculations for a 1D interface. The results reveal that the illuminated topography can be recovered directly from the measured reflected intensities. This is achieved through an analysis of the Patterson function, the Fourier transform of the scattering intensity (as a function of lateral momentum transfer, Q, at fixed vertical momentum transfer, Q). Specifically, a second-order Patterson function is defined that reveals the discrete set of separations and contrast factors (i.e. the product of changes in the effective scattering factor) associated with discontinuities in the effective interfacial topography. It is shown that the topography is significantly overdetermined by the measurements, and an algorithm is described that recovers the actual topography through a deterministic sorting of this information.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7331882PMC
http://dx.doi.org/10.1107/S2053273320003046DOI Listing

Publication Analysis

Top Keywords

interfacial topography
12
coherent x-ray
8
x-ray reflectivity
8
model calculations
8
calculations interface
8
patterson function
8
momentum transfer
8
topography
6
direct recovery
4
recovery interfacial
4

Similar Publications

Biomimetic patterning emerges as a promising antibiotic-free approach to protect medical devices from bacterial adhesion and biofilm formation. The main advantage of this approach lies in its simplicity and scalability for industrial applications. In this study, we employ it to produce antibacterial coatings based on silicone materials, widely used in the healthcare industry.

View Article and Find Full Text PDF

Herein, a WO@TCN photocatalyst was successfully synthesized using a self-assembly method, which demonstrated effectiveness in degrading organic dyestuffs and photocatalytic evolution of H. The synergistic effect between WO and TCN, along with the porous structure of TCN, facilitated the formation of a heterojunction that promoted the absorption of visible light, accelerated the interfacial charge transfer, and inhibited the recombination of photogenerated electron-hole pairs. This led to excellent photocatalytic performance of 3%WO@TCN in degrading TC and catalyzing H evolution from water splitting under visible-light irradiation.

View Article and Find Full Text PDF

Hypothesis: We hypothesise that superhydrophobic surfaces can achieve effective interfacial slip and drag reduction even under non-Newtonian, shear-thinning fluid flows. Unlike Newtonian fluids, where slip is primarily influenced by viscosity and surface tension, we anticipate that the shear-thinning nature of these fluids may enhance slip length and drag reduction.

Experiments And Numerical Analysis: The superhydrophobic surfaces used in this study, featuring a dual-scale random topography, were fabricated via a spray coating process, and low-concentration xanthan gum solutions (50-250 ppm) were used as model shear-thinning fluids of low elasticity.

View Article and Find Full Text PDF

Suppressing Friction-Induced Stick-Slip Vibration and Noise of Zinc-Coated Steel through Temper Rolling.

Langmuir

January 2025

Key Laboratory of Electromagnetic Processing of Materials (Ministry of Education), Northeastern University, Shenyang 110819, China.

The stick-slip phenomenon as a prevalent friction instability poses significant challenges to industry, including frictional vibration, reduced precision, and noise generation. The interfacial interactions between asperities on the surface of materials are critical in influencing stick-slip behavior. This study focused on modifying the asperities on the surface of zinc-coated steel through temper rolling as a new approach to suppress friction-induced stick-slip vibration and noise.

View Article and Find Full Text PDF

Cellulose Acetate Butyrate-Based In Situ Gel Comprising Doxycycline Hyclate and Metronidazole.

Polymers (Basel)

December 2024

Program of Pharmaceutical Engineering, Department of Industrial Pharmacy, Faculty of Pharmacy, Silpakorn University, Nakhon Pathom 73000, Thailand.

Cellulose acetate butyrate is a biodegradable cellulose ester bioplastic produced from plentiful natural plant-based resources. Solvent-exchange-induced in situ gels are particularly promising for periodontitis therapy, as this dosage form allows for the direct delivery of high concentrations of antimicrobial agents to the localized periodontal pocket. This study developed an in situ gel for periodontitis treatment, incorporating a combination of metronidazole and doxycycline hyclate, with cellulose acetate butyrate serving as the matrix-forming agent.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!