The use of coherent X-ray reflectivity to recover interfacial topography is described using model calculations for a 1D interface. The results reveal that the illuminated topography can be recovered directly from the measured reflected intensities. This is achieved through an analysis of the Patterson function, the Fourier transform of the scattering intensity (as a function of lateral momentum transfer, Q, at fixed vertical momentum transfer, Q). Specifically, a second-order Patterson function is defined that reveals the discrete set of separations and contrast factors (i.e. the product of changes in the effective scattering factor) associated with discontinuities in the effective interfacial topography. It is shown that the topography is significantly overdetermined by the measurements, and an algorithm is described that recovers the actual topography through a deterministic sorting of this information.
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http://dx.doi.org/10.1107/S2053273320003046 | DOI Listing |
Polymers (Basel)
January 2025
Institute of Biochemistry and Genetics, Subdivision of the Ufa Federal Research Center of the Russian Academy of Sciences, Ufa 450054, Russia.
Biomimetic patterning emerges as a promising antibiotic-free approach to protect medical devices from bacterial adhesion and biofilm formation. The main advantage of this approach lies in its simplicity and scalability for industrial applications. In this study, we employ it to produce antibacterial coatings based on silicone materials, widely used in the healthcare industry.
View Article and Find Full Text PDFMolecules
January 2025
Department of Applied Chemistry, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China.
Herein, a WO@TCN photocatalyst was successfully synthesized using a self-assembly method, which demonstrated effectiveness in degrading organic dyestuffs and photocatalytic evolution of H. The synergistic effect between WO and TCN, along with the porous structure of TCN, facilitated the formation of a heterojunction that promoted the absorption of visible light, accelerated the interfacial charge transfer, and inhibited the recombination of photogenerated electron-hole pairs. This led to excellent photocatalytic performance of 3%WO@TCN in degrading TC and catalyzing H evolution from water splitting under visible-light irradiation.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
School of Engineering, University of Liverpool, Liverpool, L69 3GH, United Kingdom.
Hypothesis: We hypothesise that superhydrophobic surfaces can achieve effective interfacial slip and drag reduction even under non-Newtonian, shear-thinning fluid flows. Unlike Newtonian fluids, where slip is primarily influenced by viscosity and surface tension, we anticipate that the shear-thinning nature of these fluids may enhance slip length and drag reduction.
Experiments And Numerical Analysis: The superhydrophobic surfaces used in this study, featuring a dual-scale random topography, were fabricated via a spray coating process, and low-concentration xanthan gum solutions (50-250 ppm) were used as model shear-thinning fluids of low elasticity.
Langmuir
January 2025
Key Laboratory of Electromagnetic Processing of Materials (Ministry of Education), Northeastern University, Shenyang 110819, China.
The stick-slip phenomenon as a prevalent friction instability poses significant challenges to industry, including frictional vibration, reduced precision, and noise generation. The interfacial interactions between asperities on the surface of materials are critical in influencing stick-slip behavior. This study focused on modifying the asperities on the surface of zinc-coated steel through temper rolling as a new approach to suppress friction-induced stick-slip vibration and noise.
View Article and Find Full Text PDFPolymers (Basel)
December 2024
Program of Pharmaceutical Engineering, Department of Industrial Pharmacy, Faculty of Pharmacy, Silpakorn University, Nakhon Pathom 73000, Thailand.
Cellulose acetate butyrate is a biodegradable cellulose ester bioplastic produced from plentiful natural plant-based resources. Solvent-exchange-induced in situ gels are particularly promising for periodontitis therapy, as this dosage form allows for the direct delivery of high concentrations of antimicrobial agents to the localized periodontal pocket. This study developed an in situ gel for periodontitis treatment, incorporating a combination of metronidazole and doxycycline hyclate, with cellulose acetate butyrate serving as the matrix-forming agent.
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