Steering alkyne homocoupling with on-surface synthesized metal-organic complexes.

Chem Commun (Camb)

Donostia International Physics Center (DIPC), 20018 San Sebastián, Spain. and Centro de Física de Materiales (CFM-MPC), CSIC-UPV/EHU, 20018 San Sebastián, Spain and Ikerbasque, Basque Foundation for Science, 48013 Bilbao, Spain.

Published: July 2020

We report a multi-step on-surface synthesis strategy. The first step consists in the surface-supported synthesis of metal-organic complexes, which are subsequently used to steer on-surface alkyne coupling reactions. In addition, we analyze and compare the electronic properties of the different coupling motifs obtained.

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Source
http://dx.doi.org/10.1039/d0cc03779fDOI Listing

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