In this study, pyrolysis kinetics and thermodynamic parameters of Safflower residues (SR) obtained from oil extraction were investigated by using TG/DSC-FTIR and py-GC/MS. Thermal analysis was performed from ambient temperature to 750 °C under a nitrogen atmosphere. The first-order reaction kinetics model was applied to thermal analysis data to determine apparent kinetic parameters. Activation energy and pre-exponential factor were calculated as 76.60 kJ.mol and 1.89x10 min, respectively. The thermodynamic parameters such as the change in Gibb's free energy, the difference in enthalpy and the entropy change were calculated to be 201.36 kJ mol, 71.79 kJ mol, and -0.196 kJ mol, respectively. TG/FTIR analysis revealed that CO, CHOH, and CC functional group as the main pyrolysis gas products. According to Py-GC/MS results of SR, the presence of high energy-containing compounds among the pyrolysis products was proved. All these results show that SR is suitable for pyrolysis to produce biofuel and/or chemicals.
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