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Identification of chemical constituents and absorbed components in rat serum of (L.) Jacq. by UPLC-Q-exactive-MS.
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College of Pharmacy, Guangxi Key Laboratory of Zhuang and Yao Ethnic Medicine, Guangxi University of Chinese Medicine, Nanning, China.
(L.) Jacq. has anti-inflammatory, analgesic, haemostatic and antioxidant effects, but its pharmacological components are still unclear.
View Article and Find Full Text PDFEffects of Multiple Treatments of Formic Acid on the Chemical Properties and Structural Features of Bamboo Powder.
Molecules
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Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Longpan Road 159, Nanjing 210037, China.
Under mild conditions, formic acid effectively separates the components of lignocellulose, removing the majority of the hemicellulose and lignin from the cellulose. However, it has not yet been determined if multiple treatments with fresh formic acid may totally remove hemicellulose and lignin. In this study, fresh formic acid was used to repeatedly pretreat the bamboo powder, and the effect of multiple treatments on the physicochemical structure of the bamboo powder was investigated using changes in fractions, enzymatic hydrolysis, hydrophilicity, cellulose crystallinity, and lignin structure.
View Article and Find Full Text PDFNickel-Catalyzed Cyclization/Carbonylation Reaction of -Allylbromoacetamides with Arylboronic Acids toward 2-Pyrrolidinones.
Org Lett
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Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023 Dalian, Liaoning, People's Republic of China.
A straightforward and efficient nickel-catalyzed cyclization/carbonylation transformation of -allylbromoacetamides toward the synthesis of 2-pyrrolidinone derivatives has been developed with arylboronic acids as the reaction partner. This transformation proceeds through a sequential single-electron-transfer pathway via 5-- cyclization and carbonyl insertion steps, furnishing a variety of 2-pyrrolidinone derivatives in good yields. Various useful functional groups were well tolerated.
View Article and Find Full Text PDF[Promotion of sp. on the photosynthetic growth of microalgae exposed to high concentrations of formate].
Sheng Wu Gong Cheng Xue Bao
January 2025
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China.
Formate is an important solar fuel, with large application potential in bioconversion. Especially, the win-win collaboration is achieved when formate is applied to the cultivation of microalgae, which combines the advantages from both artificial and natural photosynthesis. However, the inhibition of formate on the photosynthetic electron transport hinders the application of formate at high concentrations.
View Article and Find Full Text PDFEffects of Annealing Conditions on the Catalytic Performance of Anodized Tin Oxide for Electrochemical Carbon Dioxide Reduction.
Nanomaterials (Basel)
January 2025
Center for Sustainable Future Technologies @POLITO, Istituto Italiano di Tecnologia, Via Livorno 60, 10144 Turin, Italy.
The electrochemical reduction of CO (CORR) to value-added products has garnered significant interest as a sustainable solution to mitigate CO emissions and harness renewable energy sources. Among CORR products, formic acid/formate (HCOOH/HCOO) is particularly attractive due to its industrial relevance, high energy density, and potential candidate as a liquid hydrogen carrier. This study investigates the influence of the initial oxidation state of tin on CORR performance using nanostructured SnO catalysts.
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