AI Article Synopsis

  • The study measures the diamagnetic deflection of anthracene and adamantane using a long-baseline matter-wave interferometer.
  • The extracted magnetic susceptibilities show that adamantane's value aligns with predictions (-8.0 ± 1.1 m kg), while anthracene has a surprisingly higher susceptibility (-13.6 ± 1.3 m kg).
  • This increased susceptibility in anthracene is attributed to its magnetic anisotropy and partial alignment in the molecular beam, affecting the observed deflection.

Article Abstract

We measure the diamagnetic deflection of anthracene and adamantane in a long-baseline matter-wave interferometer. From the nanometer-level deflection we extract the magnetic susceptibilities of the molecules which we compare with calculations and previous results. Adamantane yields an isotropic average mass susceptibility of -8.0 ± 1.1 m kg, consistent with expectations, while anthracene yields a higher-than-anticipated value of -13.6 ± 1.3 m kg. We attribute the high anthracene value to the planar aromatic molecule's magnetic anisotropy and partial alignment in the molecular beam, and estimate the magnitude of the effect on the observed deflection.

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http://dx.doi.org/10.1039/d0cp02211jDOI Listing

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