Hydrothermal synthesis of fluorescent carbon dots from gardenia fruit for sensitive on-off-on detection of Hg and cysteine.

Spectrochim Acta A Mol Biomol Spectrosc

Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, PR China. Electronic address:

Published: October 2020

AI Article Synopsis

  • Nitrogen and sulfur co-doped carbon dots (N/S-CDs) are created using gardenia fruit through a simple hydrothermal process, resulting in nearly spherical particles about 2.1 nm in size.
  • These N/S-CDs show outstanding fluorescence stability across various pH levels and sodium chloride concentrations, with a notable quantum yield of 10.7%.
  • They can detect mercury by turning off their fluorescence and can be restored by adding cysteine, making them a practical sensor for environmental and biological applications.

Article Abstract

Nitrogen and sulfur co-doped carbon dots (N/S-CDs) were prepared by a simple hydrothermal method using gardenia fruit as precursor. The N/S-CDs are nearly spherical particles with a size of 2.1 nm and possess excellent fluorescence stability in a wide pH range and high NaCl concentrations, as well as under UV light irradiation. The absolute quantum yield (QY) without any surface modification reaches up to 10.7%. Meanwhile, the N/S-CDs can be quenched by Hg (turn-off), while the quenched fluorescence can be recovered (turn-on) by introducing cysteine (Cys), with linear ranges of 2-20 μM for Hgand 0.1-2.0 μM for Cys. On the basis of the on-off-on sensing mode, the N/S-CDs can be used to detect Hg and Cys. Hence, the N/S-CDs would be a promising sensor in environmental and biological analysis.

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http://dx.doi.org/10.1016/j.saa.2020.118598DOI Listing

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