The concept of recirculation of diluate/concentrate stream is implemented in multi-stage ion concentration polarization (ICP) desalination to deal with the issue of uncontrolled concentrate streams and deteriorated overall recovery rate to treat highly concentrated oil produce water from refineries. An improved empirical optimization model was established to calculate total energy consumption for operating cost and required membrane area for capital cost for a given set of operating parameters, feed salinity, salt removal ratio, and flow velocity. Using the empirical optimization model, a techno-economic analysis is performed to evaluate the feasibility of two-stage ICP system with recirculation loops. Brine of 160 g/kg is set as the system feed stream, whereas other operating conditions such as dilaute and concentrate streams are being controlled/fixed with 20 g/kg and ~250 g/kg respectively. Also, the system can be flexibly controlled to produce a specific concentration of product water and a recovery ratio with a corresponding water cost. With careful choices of recirculation rates, one can significantly increase the recovery ratio of two-stage ICP brine treatment process (from 25% to 39%) with only minor increase in overall cost (from $16.4-25.9/m to $20.6-22.54/m), which is favourable for brine waste treatment application.
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http://dx.doi.org/10.1016/j.jenvman.2020.110788 | DOI Listing |
ACS Environ Au
January 2025
Dow Centre for Sustainable Engineering Innovation, School of Chemical Engineering, The University of Queensland, Brisbane, QLD 4072, Australia.
The global transition to clean energy technologies has escalated the demand for lithium (Li), a critical component in rechargeable Li-ion batteries, highlighting the urgent need for efficient and sustainable Li extraction methods. Nanofiltration (NF)-based separations have emerged as a promising solution, offering selective separation capabilities that could advance resource extraction and recovery. However, an NF-based lithium extraction process differs significantly from conventional water treatment, necessitating a paradigm shift in membrane materials design, performance evaluation metrics, and process optimization.
View Article and Find Full Text PDFWaste Manag
January 2025
Department of Mechanical Engineering, University of Alberta, 10-203 Donadeo Innovation Centre for Engineering, Edmonton, Alberta T6G 1H9, Canada. Electronic address:
Bitumen-derived petcoke contains significant quantities of vanadium, recoverable from the fly ash formed during combustion. Despite efforts to process vanadium recovery from petcoke, detailed cost information, critical for stakeholders and decision-makers, remains absent in the public domain. To address this gap, we developed data-intensive techno-economic models specifically for vanadium recovery from petcoke fly ash.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Chemical Engineering, Worcester Polytechnic Institute, Worcester, MA, USA.
The economic feasibility of low-carbon ammonia production pathways, such as steam methane reforming with carbon capture and storage, biomass gasification, and electrolysis, is assessed under various policy frameworks, including subsidies, carbon pricing, and renewable hydrogen regulations. Here, we show that employing a stochastic techno-economic analysis at the plant level and a net present value approach under the US Inflation Reduction Act reveals that carbon capture and biomass pathways demonstrate strong economic potential due to cost-effectiveness and minimal public support needs. Conversely, the electrolytic pathway faces significant economic challenges due to higher costs and lower efficiency.
View Article and Find Full Text PDFWaste Manag
January 2025
Idaho National Laboratory, Idaho Falls, ID, USA.
Flexible plastic packaging (FPP) is a growing waste source in the United States. Currently, FPP has a recycling rate of only 2% in the U.S.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
Saudi Aramco, Dhahran 31311, Saudi Arabia.
Amid ambitious net-zero goals and growing demands for freight logistics, addressing the climate challenges posed by the heavy-duty truck (HDT) sector is an urgent and pivotal task. This study develops an integrated HDT model by incorporating vehicle dynamic simulation and life cycle analysis to quantify energy consumption, greenhouse gas (GHG) emissions, and total cost of ownership associated with three emerging powertrain technologies in various truck use scenarios in China, including battery electric, fuel cell electric, and hydrogen combustion engine trucks. The results reveal varying levels of economic suitability for these powertrain alternatives depending on required driving ranges and duty cycles: the battery electric for regional-haul applications, the hydrogen fuel cell for longer-haul and low-load driving conditions, and the hydrogen combustion engine to meet high power requirements.
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