The ever-increasing demand for carbon fibre reinforced polymers (CFRP) and stringent environmental legislation have driven the research into recycling and reusing the CFRP waste. This paper presents a mechanical recycling process of CFRP and the application of the recyclates as reinforcement for epoxy foams. The CFRP was mechanically processed using a jet mill. Up to 10 wt% of the CFRP recyclates, without separation of fibre-rich portion and resin-rich portion, was added into epoxy foams. The compressive modulus and strength of the epoxy foams increased from 288 MPa and 7.0 MPa, respectively, to 1060 MPa and 22.8 MPa, respectively, accompanied with an increase in foam density from 0.37 g cm to 0.68 g cm. Consequently, the specific compressive modulus and strength (normalised against density) increased from 789 MPa cm g and 19.1 MPa cm g for unreinforced foam to 1563 MPa cm g and 33.5 MPa cm g for CFRP recyclates reinforced foam, representing a 98% and 75% improvement, respectively. These results demonstrate that the CFRP recyclates have excellent reinforcing ability for epoxy foams.
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http://dx.doi.org/10.1016/j.jenvman.2020.110766 | DOI Listing |
Materials (Basel)
October 2024
Department of Building Materials Science, National Research Moscow State University of Civil Engineering, Yaroslavskoe sh. 26, 129337 Moscow, Russia.
An effective type of polymer heat-insulating material (foams) based on reactive oligomers is casting epoxy foams with high technological and operational parameters. However, polyepoxide foams are highly flammable, which significantly restrains their application in the construction industry. The aim of this work was to develop effective methods for reducing the flammability of filling epoxy foams.
View Article and Find Full Text PDFRSC Adv
October 2024
Nuclear Materials Authority P.O. Box 530 Maadi Cairo Egypt
Epoxy-modified phosphorus pentasulfide (EPMPS) formulation was developed for the supported recovery of uranium from aquatic environments. The selected components of the prepared formulation were tailored to produce a rigid foamed polymeric material that was rich in phosphorus, nitrogen, sulfur and oxygen atoms, thus increasing chelating bonding possibilities with uranium. FT-IR and SEM were applied to physically characterize the resulting sorbent.
View Article and Find Full Text PDFInt J Biol Macromol
November 2024
Hubei Provincial Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Wuhan 430068, China.. Electronic address:
Bead foaming technique is regarded as a highly promising method for preparing foams with complex geometries and high expansion ratios. The biodegradability of poly(butylene adipate-co-terephthalate) (PBAT) has garnered significant attention in the field of foam materials. However, due to inherent disadvantages such as low melt strength and low modulus, PBAT faces challenges during bead foaming.
View Article and Find Full Text PDFTurk J Chem
January 2024
Department of Chemistry, Faculty of Arts and Science, Yıldız Technical University, İstanbul, Turkiye.
In recent years, there has been an increasing interest in producing new materials that use renewable resources and halogen-free flame retardants with nonleaching properties. This research focuses on designing and synthesizing phosphorus-nitrogen-based biopolyols for use in polyurethane (PU) foam production. Polyol (ESBO-DYM) with dual functionalities, renewability, and nonflammability is synthesized through the epoxy ring-opening reaction of epoxidized soybean oil with phosphorus and nitrogen-containing tetraol products (DYM).
View Article and Find Full Text PDFPolymers (Basel)
June 2024
Department of Chemistry, Pittsburg State University, 1701 South Broadway Street, Pittsburg, KS 66762, USA.
Over the past few decades, polymer composites have received significant interest and become protagonists due to their enhanced properties and wide range of applications. Herein, we examined the impact of filler and flame retardants in hemp seed oil-based rigid polyurethane foam (RPUF) composites' performance. Firstly, the hemp seed oil (HSO) was converted to a corresponding epoxy analog, followed by a ring-opening reaction to synthesize hemp bio-polyols.
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