Radon is one of the main causes of environmental pollution and lung cancer. The precipitation of radon from porous media is affected by the coupling of heat and moisture, which has not been considered in the existing knowledge. We present a model for predicting radon migration in porous media. This model combines the heat-air-moisture (HAM) coupling model of porous media with a radon migration model to establish three-dimensional partial differential equations for steady-state radon migration under HAM coupling conditions. The finite element method (FEM) was used to obtain a numerical solution. Experimental verification showed that the model had high calculation accuracy; the calculated maximum relative error did not exceed 15%. The results of the model were compared with the results of a conventional model that does consider the coupling of heat and humidity; the results showed significant differences in the radon concentrations and radon flux distribution curves for the two models. The newly developed model revealed that there is a significant coupling effect between migration and the distribution of the temperature field, the humidity field, and radon flux in unsaturated porous media. The radon exhalation rate on the surface of porous media increases linearly with the increase of permeability. The exhalation rate decreased exponentially with the increase in relative humidity. When the trend of the temperature gradient was consistent with the concentration gradient, the radon exhalation rate decreased linearly with the increase in temperature gradient. We establish a new model to study the radon migration in porous media under the coupling of heat and moisture. The model provides a theoretical basis for an effective and accurate analysis of the impact of radon exhalation on the environment.
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http://dx.doi.org/10.1007/s11356-020-09374-z | DOI Listing |
Gels
December 2024
Institute of Natural Sciences and Technosphere Safety, Sakhalin State University, 693000 Yuzhno-Sakhalinsk, Russia.
A new composite material with enhanced sorption-selective properties for uranium recovery from liquid media has been obtained. Sorbents were synthesized through a polycondensation reaction of a mixture of 4-amino-N'-hydroxy-1,2,5-oxadiazole-3-carboximidamide (hereinafter referred to as amidoxime) and SiO in an environment of organic solvents (acetic acid, dioxane) and highly porous SiO. To establish optimal conditions for forming the polymer sorption-active part and the synthesis as a whole, a series of composite adsorbents were synthesized with varying amidoxime/matrix ratios (35/65, 50/50, 65/35).
View Article and Find Full Text PDFJ Environ Manage
January 2025
BQE Water, Vancouver, BC, Canada.
Biological semi-passive mine water treatment technologies are used in the mining industry as an alternative to or in conjunction with active treatment systems to remediate mine impacted water (MIW) containing nitrate and selenium oxyanions such as selenate and selenite. In semi-passive biological treatment systems, MIW is pumped through a saturated, porous media (either a gravel bed or waste rock) which provides ample surface area for biofilm growth and the creation of anoxic, subaqueous environments. Additional nutrients and carbon sources are pumped into the system to encourage the growth of microbes that biochemically reduce selenate and selenite to insoluble reduced Se species such as selenium nanoparticles (SeNP) by respiring selenate and selenite.
View Article and Find Full Text PDFChaos
January 2025
Department of Civil Engineering, The University of Hong Kong, HKSAR 999077, China.
Porous earth materials exhibit large-scale deformation patterns, such as deformation bands, which emerge from complex small-scale interactions. This paper introduces a cross-diffusion framework designed to capture these multiscale, multiphysics phenomena, inspired by the study of multi-species chemical systems. A microphysics-enriched continuum approach is developed to accurately predict the formation and evolution of these patterns.
View Article and Find Full Text PDFJ Chromatogr A
January 2025
Dipartimento di Ingegneria Chimica Materiali Ambiente, Sapienza Università di Roma, Italy. Electronic address:
The exact moment method for the determination of the dispersion tensor in retentive porous media has been adopted to compute the dispersion coefficients, the plate height curves and the kinetic performance factors of eight different 3D printable stationary phases based on triply periodic minimal surfaces (TPMS). The two cases in which the stationary phase is impermeable (hydrodynamic dispersion) or superficially retentive have been analyzed in detail. The Carman-Kozeny relationship between permeability K, hydraulic diameter d and hydrodynamic tortuosity τ holds true for all the geometries investigated with a unique shape coefficient K.
View Article and Find Full Text PDFTob Prev Cessat
January 2025
School of Public Health, Kwame Nkrumah University of Science & Technology, Kumasi, Ghana.
The illicit trade of tobacco products trade continues to challenge tobacco control efforts in several African countries, including Ghana. Ghana recently ratified the Framework Convention for Tobacco Control (FCTC) Protocol to Eliminate Illicit Trade in Tobacco Products ('the Protocol'). This Protocol aims to eliminate all kinds of illicit tobacco.
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