We report a highly effective metal-free catalytic procedure for the functionalization of silsesquioxanes via dehydrocoupling of various POSS silanols with hydrosilanes in the presence of commercially available tris(pentafluorophenyl)borane B(CF). This approach enables the unprecedented one-pot synthesis of valuable silsesquioxane derivatives under mild conditions, with no corrosive byproducts formed in the process.
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| http://dx.doi.org/10.1021/acs.inorgchem.0c01125 | DOI Listing |
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