Metal-free generation of hydroxyl radicals by benzoate-mediated decomposition of peroxides.

Chem Commun (Camb)

State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, China.

Published: July 2020

A type of metal-free organic photo-Fenton-like reaction was developed, which was realized by a combination of UV with benzoates and peroxides. The findings here not only provide a novel ˙OH production pathway, but also shed new light on the accurate quantification, better use or prevention of ˙OH in many scenarios.

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http://dx.doi.org/10.1039/d0cc02633fDOI Listing

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