In a superionic (SI) ice phase, oxygen atoms remain crystallographically ordered while protons become fully diffusive as a result of intramolecular dissociation. Ice VII's importance as a potential candidate for a SI ice phase has been conjectured from anomalous proton diffusivity data. Theoretical studies indicate possible SI prevalence in large-planet mantles (e.g., Uranus and Neptune) and exoplanets. Here, we realize sustainable SI behavior in ice VII by means of externally applied electric fields, using state-of-the-art nonequilibrium ab initio molecular dynamics to witness at first hand the protons' fluid dance through a dipole-ordered ice VII lattice. We point out the possibility of SI ice VII on Venus, in its strong permanent electric field.
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http://dx.doi.org/10.1126/sciadv.aaz2915 | DOI Listing |
Inorg Chem
January 2025
Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577, Japan.
Sodium borohydride dihydrate (NaBH·2HO) forms through dihydrogen bonding between the hydridic hydrogen of the BH ion and the protonic hydrogen of the water molecule. High-pressure structural changes in NaBH·2HO, observed up to 11 GPa through X-ray diffraction and Raman scattering spectroscopy, were analyzed to assess the influence of dihydrogen bonds on its crystal structure. At approximately 4.
View Article and Find Full Text PDFEnviron Monit Assess
October 2024
Dept. of Natural and Environmental Risks, Regional Agency for Environmental Protection of the Piedmont Region (ARPA Piemonte), Via Pio VII, 9, 10135, Turin, Italy.
Intact rock glaciers (RG) are considered valuable water storage because containing permafrost ice volumes. The hydrological relevance of RG is forecasted to increase with respect to glaciers under climate change scenarios, as well as RG's role as water resources in alpine basins for multiple uses. Besides the assessment of water amount stored in intact rock glaciers, the evaluation of water quality is of primary importance.
View Article and Find Full Text PDFAllergy
December 2024
Swiss Institute of Allergy and Asthma Research (SIAF), University of Zurich, Davos, Switzerland.
The prevalence of many chronic noncommunicable diseases has been steadily rising over the past six decades. During this time, over 350,000 new chemical substances have been introduced to the lives of humans. In recent years, the epithelial barrier theory came to light explaining the growing prevalence and exacerbations of these diseases worldwide.
View Article and Find Full Text PDFNat Commun
September 2024
CEA, DAM, DIF, F-91297, Arpajon, France.
Water can be dynamically over-compressed well into the stability field of ice VII. Whether water then transforms into ice VII, vitreous ice or a metastable novel crystalline phase remained uncertain. We report here the freezing of over-compressed water to ice VII by time-resolved X-ray diffraction.
View Article and Find Full Text PDFNat Commun
June 2024
Geochemical Research Center, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan.
Hydrogen bond symmetrisation is the phenomenon where a hydrogen atom is located at the centre of a hydrogen bond. Theoretical studies predict that hydrogen bonds in ice VII eventually undergo symmetrisation upon increasing pressure, involving nuclear quantum effect with significant isotope effect and drastic changes in the elastic properties through several intermediate states with varying hydrogen distribution. Despite numerous experimental studies conducted, the location of hydrogen and hence the transition pressures reported up to date remain inconsistent.
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