Fluid commonly flows in response to an external pressure gradient. However, when a tunnel-containing hydrogel is immersed in water, spontaneous flow occurs through the tunnel without any pressure gradient. We confirmed this flow in a wide range of plant- and animal-derived hydrogels. The flow appears to be driven by axial concentration gradients originating from surface activities of the tunnel wall. Those activities include (i) hydrogel-water interaction and (ii) material exchange across the tunnel boundary. Unlike pressure-driven flow, this surface-induced flow has two distinct features: incident infrared energy substantially increases flow velocity, and narrower tunnels generate faster flow. Thus, surface activities in hydrogel-lined tunnels may confer kinetic energy on the enclosed fluid, with infrared as an energy source.
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http://dx.doi.org/10.1126/sciadv.aba0941 | DOI Listing |
Mol Biol Rep
January 2025
Department of Biology, Central Tehran Branch, Islamic Azad University, Tehran, Iran.
Background: Breast carcinoma stands out as the most widespread invasive cancer and the top contributor to cancer-related mortality in women. Nanoparticles have emerged as promising tools in cancer detection, diagnosis, and prevention. In this study, the antitumor and apoptotic capability of silver nanoparticles synthesized through Scrophularia striata extract (AgNPs-SSE) was investigated toward breast cancer cells.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
Department of Environmental Sciences, University of Virginia, Charlottesville, Virginia 22904, United States.
Industrialized swine facilities adversely affect the health and well-being of Eastern North Carolina residents in the U.S. and are an issue of environmental racism.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Institute of Chemistry, Department of Fundamental Chemistry, University of São Paulo, Av. Prof. Lineu Prestes, 748 - Butantã, São Paulo, 05508-900, Brazil.
The conformational isomerization of nitrous acid (HONO) promoted by excitation of the or stretching normal coordinates is the first observed case of an infrared-induced photochemical reaction. The energy captured by the excited normal modes is redistributed into a highly excited vibrational level of the torsion normal coordinate, which is the isomerization reaction coordinate. Herein, we present simple numerical methods to qualitatively investigate the coupling between the normal coordinates and the possible gateways for vibrational energy redistribution leading to the isomerization process.
View Article and Find Full Text PDFHeliyon
January 2025
Nuclear Chemistry Division, Department of Chemistry, Atomic Energy Commission, P. O. Box: 9061, Damascus, Syrian Arab Republic.
Molecular scale information is needed to understand ions coordination to mineral surfaces and consequently to accelerate the design of improved adsorbents. The present work reports on the use of two-dimensional correlation Fourier Transform infra-red spectroscopy (2D-COS-FTIR) and hetero 2D-COS-FTIR- X-ray diffraction (XRD) to probe the mechanism of Cr(VI) removal from aqueous solutions by activated carbon (AC) and its composite with PWO (AC-composite). The adsorption data at an initial Cr(VI) concentration of 320 mg L (320 ppm) revealed maximum adsorption capacities of 65 mg g for AC and 73 mg g for AC-composite, corresponding to removal percentages of 83 % and 94 %, respectively.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
January 2025
Department of Physics and Astronomy, University of Exeter, Exeter EX4 4QL, U.K.
Many different types of nanoparticles have been developed for photothermal therapy (PTT), but directly comparing their efficacy as heaters and determining how they will perform when localized at depth in tissue remains complex. To choose the optimal nanoparticle for a desired hyperthermic therapy, it is vital to understand how efficiently different nanoparticles extinguish laser light and convert that energy to heat. In this paper, we apply photothermal mass conversion efficiency (η ) as a metric to compare nanoparticles of different shapes, sizes, and conversion efficiencies.
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