An orthorhombic modification of (Fe,Ni)P, allabogdanite, found in iron meteorites was considered to be thermodynamically stable at pressures above 8 GPa and temperatures of 1673 K according to the results of recent static high-pressure and high-temperature experiments. A hexagonal polymorphic modification of (Fe,Ni)P, barringerite, was considered to be stable at ambient conditions. Experimental investigation through the solid-state synthesis supported by ab initio calculations was carried out to clarify the stability fields of (Fe,Ni)P polymorphs. Both experimental and theoretical studies show that FeP-allabogdanite is a low-temperature phase stable at ambient conditions up to a temperature of at least 773 K and, therefore, is not necessarily associated with high pressures. This is consistent with the textural relationships of allabogdanite in iron meteorites.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7265559PMC
http://dx.doi.org/10.1038/s41598-020-66039-0DOI Listing

Publication Analysis

Top Keywords

iron meteorites
12
fenip allabogdanite
8
modification fenip
8
allabogdanite iron
8
stable ambient
8
ambient conditions
8
fenip
4
allabogdanite ambient
4
ambient pressure
4
pressure phase
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!