An orthorhombic modification of (Fe,Ni)P, allabogdanite, found in iron meteorites was considered to be thermodynamically stable at pressures above 8 GPa and temperatures of 1673 K according to the results of recent static high-pressure and high-temperature experiments. A hexagonal polymorphic modification of (Fe,Ni)P, barringerite, was considered to be stable at ambient conditions. Experimental investigation through the solid-state synthesis supported by ab initio calculations was carried out to clarify the stability fields of (Fe,Ni)P polymorphs. Both experimental and theoretical studies show that FeP-allabogdanite is a low-temperature phase stable at ambient conditions up to a temperature of at least 773 K and, therefore, is not necessarily associated with high pressures. This is consistent with the textural relationships of allabogdanite in iron meteorites.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7265559 | PMC |
http://dx.doi.org/10.1038/s41598-020-66039-0 | DOI Listing |
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