Rapid synchronous synthesis of Ag nanoparticles and Ag nanoparticles/holocellulose nanofibrils: Hg(II) detection and dye discoloration.

Carbohydr Polym

Department of Forest Biomaterials Engineering, College of Forest and Environmental Sciences, Kangwon National University, Chuncheon 24341, Republic of Korea. Electronic address:

Published: July 2020

A novel microwave-assisted green method that synchronously synthesizes silver nanoparticles (AgNPs) and AgNPs decorated holocellulose nanofibrils (AgNPs/HCNF) within a minute and without using a reducing agent is reported. As obtained nanomaterials were well characterized using various analytical techniques. AgNPs applied as a colorimetric probe for the selective recognition of Hg(II) (linear range 10-200 μg L, detection limit 1.16 μg L). The probe was able to quantify Hg(II) in spiked tap, bore, and lake water samples and paper strips were developed to facilitate the onsite detection. Furthermore, freeze-drying of the AgNPs/HCNF nanocomposite produced aerogel that served as an excellent catalyst for the reduction of Congo red and methylene blue. The aerogel was easily recovered and reused without a decrease in activity or deterioration of its structure for five cycles. These results indicate the great potential of the AgNPs/HCNF aerogel for waste water treatment and catalytic applications.

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http://dx.doi.org/10.1016/j.carbpol.2020.116356DOI Listing

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