In this study, a high aluminum and chromium Fe-B-C coating was prepared using laser cladding on 2Cr13 steel substrate. The microstructure, microhardness, and wear resistance of the high aluminum and chromium Fe-B-C coating were investigated. The results show that this dense coating possesses good metallurgical bond with the substrate. The microstructure is mainly composed of α-(Fe, Cr, Al) lath martensite, orthorhombic MB boride, orthogonal MC, and orthorhombic MC carbides. The microhardness of the coating can reach 620 HV which is 3.3-times higher than that (190 HV) of the substrate. The coating shows a lower friction coefficient of 0.75 than that of the substrate (1.08). The wear rates of the substrate and the coating are 0.295 mg/min and 0.103 mg/min, respectively, indicating the coating exhibits excellent wear resistance. The wear mechanism transforms severe adhesive wear and abrasive wear of the substrate to slight abrasive wear of the coating. The results can provide technical support to improve the properties of the Fe-based laser cladded coating.
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http://dx.doi.org/10.3390/ma13112443 | DOI Listing |
Adv Sci (Weinh)
January 2025
State Key Laboratory of Chemical Oncogenomics, School of Chemical Biology and Biotechnology, Peking University Shenzhen Graduate School, Shenzhen, 518055, P. R. China.
Adjuvants are non-specific immune enhancers commonly used to improve the responsiveness and persistence of the immune system toward antigens. However, due to the undefined chemical structure, toxicity, non-biodegradability, and lack of design technology in many existing adjuvants, it remains difficult to achieve substantive breakthroughs in the adjuvant research field. Here, a novel adjuvant development strategy based on stapling peptides is reported to overcome this challenge.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Light Industry and Food Engineering, Nanjing Forestry University, Nanjing 210037 China. Electronic address:
The mechanical flexibility and high conductivity of hydrogel electrolytes are crucial for their application in supercapacitors. In this study, we developed hydrogel electrolyte based on lignocellulose nanofibers (LCNFs) through nanofibrillation and self-catalytic gelation in a glycerinum/choline chloride/aluminum chloride hexahydrate (Gly/ChCl/AlCl·6HO) metal-based neutral deep eutectic solvent (DES) system. The lignin-Al self-catalytic mechanism offered an eco-friendly and sustainable method for synthesizing hydrogel electrolytes, while enhancing their ionic conductivity.
View Article and Find Full Text PDFDalton Trans
January 2025
Institute of Inorganic Chemistry, Georg-August-Universität Göttingen, Göttingen Tammannstrasse 4, D-37077, Germany.
The reactions of LAlH (L = HC(CMeNAr), Ar = 2,6-PrCH) (1) with diphenylphosphane oxide [PhP(O)H], diphenylphosphinamide [PhP(O)NH], and diaryl/alkyl phosphane [(RO)P(O)H (R = Ph, or Pr)] afford their corresponding compounds with compositions LAl(H)OP(Ph) (2), LAl[OP(Ph)] (3), LAl{[N(H)P(O)(Ph)][OP(Ph)]} (4), LAl(OPr) (5), and LAl(OPh) (6), respectively. These reactions probably undergo a process of dehydrogenation coupling, deaminating dehydrogenation coupling, or chain-breaking coupling. It is noteworthy to mention that the reaction of compound 1 with 2 equiv.
View Article and Find Full Text PDFACS Appl Bio Mater
January 2025
Laboratório de Processos Eletroquímicos e Corrosão-ELETROCORR, Departamento de Metalurgia, Universidade Federal do Rio Grande do Sul, Avenida Bento Gonçalves 9500, 91501-970 Porto Alegre, Brazil.
This study presents an innovative approach to creating antibacterial aluminum surfaces by combining the antibacterial properties of silver nanoparticles (Ag NPs) with the nanoarchitecture of anodized aluminum oxide in one step. An Al-Ag alloy containing 10 wt % Ag was synthesized and anodized in 0.3 M oxalic acid.
View Article and Find Full Text PDFJ Sci Food Agric
January 2025
College of Food Science and Technology, Bohai University; Food Safety Key Lab of Liaoning Province; National & Local Joint Engineering Research Center of Storage, Processing and Safety Control Technology for Fresh Agricultural and Aquatic Products, Jinzhou, China.
Background: Multifunctional fluorescent probes have attracted much attention due to their wide range of applications and high utilization. In this study, a multifunctional fluorescent probe (E)-3-(4-(7-(4-(diphenylamino)phenyl)benzo[c] [1,2,5]thiadiazol-4-yl)phenyl)acrylic acid (TBAC) based on triphenylamine was designed and synthesized.
Results: The TBAC probe provided excellent aggregation-induced emission (AIE) performance and could be used as a fluorescent ink for printing.
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