Nontrivial topology in bulk matter has been linked with the existence of topologically protected interfacial states. We show that a gaseous plasmon polariton (GPP), an electromagnetic surface wave existing at the boundary of magnetized plasma and vacuum, has a topological origin that arises from the nontrivial topology of magnetized plasma. Because a gaseous plasma cannot sustain a sharp interface with discontinuous density, one must consider a gradual density falloff with scale length comparable to or longer than the wavelength of the wave. We show that the GPP may be found within a gapped spectrum in present-day laboratory devices, suggesting that platforms are currently available for experimental investigation of topological wave physics in plasmas.
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http://dx.doi.org/10.1103/PhysRevLett.124.195001 | DOI Listing |
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January 2025
Key Laboratory of New Energy and Rare Earth Resource Utilization of State Ethnic Affairs Commission, Key Laboratory of Photosensitive Materials & Devices of Liaoning Province, School of Physics and Materials Engineering, Dalian Minzu University, Dalian, 116600, China.
Owing to its high sensitivity, surface-enhanced Raman scattering (SERS) has immense potential for the identification of lung cancer from the variation in volatile biomarkers in the exhaled gas. However, two prevailing factors limit the application of SERS: 1) the adsorption of target molecules into SERS hotspots and 2) the detection specificity in multiple interference environments. To improve the density of the SERS hotspots, 3D Au@Ag-Au particles are prepared in a porous nanoframes (PPFs) based plasmonic structure, which facilitated a richer local electromagnetic field distribution among the Au nanocubic (NC) cores, Au-Ag porous nanoframes, and Au nanoparticles, thereby promoting the adsorption probability of gaseous aldehydes into the hotspots.
View Article and Find Full Text PDFACS Sens
December 2024
York Plasma Institute, School of Physics, Engineering and Technology, University of York, York YO10 5DD, U.K.
Nanogold is an emerging material for enhancing surface-enhanced Raman scattering (SERS), which enables the detection of hazardous analytes at trace levels. This study presents a simple, single-step plasma synthesis method to control the size and yield of Au nanoparticles by using plasma-liquid redox chemistry. The pin-based argon plasma reduces the Au precursor in under 5 min, synthesizing Au spherical particles ranging from ∼20 nm at 0.
View Article and Find Full Text PDFJ Phys Chem Lett
December 2024
ITMO University, Department of Physics and Engineering, 197101, 49 Kronverkskiy av., St. Petersburg, Russian Federation.
Hybrid metal-semiconductor nanostructures unifying plasmonic and high-refractive-index materials in a single resonant system demonstrate a wide set of unique optical properties. Such systems are a perspective for a broad palette of applications, but the link between their inner structure and optical properties is a very sensitive issue, which is still not revealed. Here, we describe the influence of internal microstructure of a hybrid gold-silicon nanoparticle (the gold nanoparticle with embedded silicon nanograins) on the up-conversion white-light photoluminescence.
View Article and Find Full Text PDFRSC Adv
September 2024
Department of Applied Chemistry, Adama Science and Technology University 1888 Adama Ethiopia
Doped semiconductor heterostructures have superior properties compared to their components. In this study, we observed the synthesis of Cu-doped ZnO/Ag/CuO heterostructure with the presence of charge transfer and visible light-harvesting properties resulting from doping and heterojunction. The porous heterostructures were prepared using the bottom-up combustion (BUC) approach.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
November 2024
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, Guangdong Basic Research Center of Excellence for Functional Molecular Engineering, School of Chemistry, IGCME, Sun Yat-Sen University, Guangzhou, 510275, China.
Efficient photocatalytic CO reduction coupled with the photosynthesis of pure HO is a challenging and significant task. Herein, using classical CO photoreduction site iron porphyrinate as the linker, Ag(I) clusters were spatially separated and evenly distributed within a new metal-organic framework (MOF), namely AgTPyP-Fe. With water as electron donors, AgTPyP-Fe exhibited remarkable performances in artificial photosynthetic overall reaction with CO yield of 36.
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