Surface motif sensitivity of dual emissive gold nanoclusters for robust ratiometric intracellular imaging.

Chem Commun (Camb)

School of Food and Biological Engineering, Engineering Research Center of Bio-process, Ministry of Education, Hefei University of Technology, Hefei, Anhui 230009, China.

Published: July 2020

Here, we report novel dual-emissive gold nanoclusters (d-Au NCs) that have two distinctive emissions (420 and 630 nm) under a single wavelength excitation. The two-stage formation mechanism evidences their sensitive response to valine and trivalent chromium ions (Cr) in completely different spectral ratiometric modes in living cells with high contrast to successfully avoid signal fluctuations.

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http://dx.doi.org/10.1039/d0cc03036hDOI Listing

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