Here, we report novel dual-emissive gold nanoclusters (d-Au NCs) that have two distinctive emissions (420 and 630 nm) under a single wavelength excitation. The two-stage formation mechanism evidences their sensitive response to valine and trivalent chromium ions (Cr) in completely different spectral ratiometric modes in living cells with high contrast to successfully avoid signal fluctuations.
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http://dx.doi.org/10.1039/d0cc03036h | DOI Listing |
J Chem Inf Model
January 2025
Department of Chemistry, Kansas State University, Manhattan, Kansas 66506, United States.
Gold nanoparticles can exhibit unique physical and chemical properties, such as plasmon resonances or photoluminescence. These nanoparticles have many atoms, which leads to high computational costs for density functional theory (DFT) calculations. In this work, we used the FLARE++ (fast learning of atomistic rare events) code and incorporated an active learning algorithm to construct force fields for gold thiolate-protected nanoclusters.
View Article and Find Full Text PDFJ Agric Food Chem
January 2025
College of Chemistry and Chemical Engineering, Jishou University, Jishou, Hunan 416000, P. R. China.
Detecting β-lactoglobulin (β-Lg) with high sensitivity and selectivity is an urgent requirement due to nearly 80% of milk anaphylaxis, such as respiratory tract, skin urticaria, and gastrointestinal disorders, being caused by β-Lg. An ultrasensitive β-Lg electrochemical aptasensor utilizing core-satellite gold nanoparticle@silver nanocluster (AuNPs@AgNCs) nanohybrids as electrocatalysts was developed. First, β-Lg aptamer was anchored on gold electrodes and AuNPs to obtain high selectivity.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
School of Biomedical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P.R. China.
Gold nanoclusters (Au NCs) protected by molecular ligands represent a new class of second-generation near-infrared (NIR-II) luminescent materials that have been widely studied. However, the photoluminescence efficiencies of most NIR-II emitting Au NCs in aqueous solution are generally lower than 0.2%, and to fully exploit the advantages of AuNCs in the NIR-II region, improving their photoluminescence efficiency has become an urgent need.
View Article and Find Full Text PDFChem Sci
January 2025
School of Chemistry and Chemical Engineering, Chongqing Key Laboratory of Chemical Theory and Mechanism, Chongqing University Chongqing 401331 China
Atomically precise gold nanoclusters have shown great promise as model electrocatalysts in pivotal electrocatalytic processes such as the hydrogen evolution reaction (HER) and carbon dioxide reduction reaction (CORR). Although the influence of ligands on the electronic properties of these nanoclusters is well acknowledged, the ligand effects on their electrocatalytic performances have been rarely explored. Herein, using [Au(SR)] nanoclusters as a prototype model, we demonstrated the importance of ligand hydrophilicity hydrophobicity in modulating the interface dynamics and electrocatalytic performance.
View Article and Find Full Text PDFNanoscale
January 2025
Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, P. R. China.
Investigating the impact of heteroatom alloying extents on regulating the cluster structures is crucial for the fabrication of cluster-based nanomaterials with customized properties. Herein, two structurally comparable PdAu ( = 1, 2) nanoclusters with a uniform surface environment but completely distinct kernel configurations were controllably synthesized and structurally determined. The single Pd-alloyed Pd1Au12 nanocluster retained an icosahedral metal framework, while the Pd2Au12 nanocluster with two Pd heteroatoms exhibited a unique toroidal configuration.
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