There are a broad range of applications for narrowband long-wave infrared (LWIR) sources, especially within the 8-12 μm atmospheric window. These include infrared beacons, free-space communications, spectroscopy, and potentially on-chip photonics. Unfortunately, commercial light-emitting diode (LED) sources are not available within the LWIR, leaving only gas-phase and quantum cascade lasers, which exhibit low wall-plug efficiencies and in many cases require large footprints, precluding their use for many applications. Recent advances in nanophotonics have demonstrated the potential for tailoring thermal emission into an LED-like response, featuring narrowband, polarized thermal emitters. In this work, we demonstrate that such nanophotonic IR emitting metamaterials (NIREMs), featuring near-unity absorption, can serve as LWIR sources with effectively no net power consumption, enabling their operation entirely by waste heat from conventional electronics. Using experimental emissivity spectra from a SiC NIREM device in concert with a thermodynamic compact model, we verify this feasibility for two test cases: a NIREM device driven by waste heat from a CPU heat sink and one operating using a low-power resistive heater for elevated temperature operation. To validate these calculations, we experimentally determine the temperature-dependent NIREM irradiance and the angular radiation pattern. We purport that these results provide a first proof-of-concept for waste heat-driven thermal emitters potentially employable in a variety of infrared application spaces.
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http://dx.doi.org/10.1021/acsomega.0c00600 | DOI Listing |
Nano Lett
January 2025
Department of Physics and Astronomy, Seoul National University, 08826 Seoul, Korea.
Quantum emitters in solid-state materials are highly promising building blocks for quantum information processing and communication science. Recently, single-photon emission from van der Waals materials has been reported in transition metal dichalcogenides and hexagonal boron nitride, exhibiting the potential to realize photonic quantum technologies in two-dimensional materials. Here, we report the generation of room temperature single-photon emission from exfoliated and thermally annealed single crystals of van der Waals α-MoO.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Institute of Physics, Lodz University of Technology, ul. Wólczańska 217/221, 90-003 Łódź, Poland.
This paper presents a novel approach to address the issue of uneven temperature distribution in one-dimensional laser arrays, specifically in gallium nitride edge-emitting lasers emitting green light of 540 nm. The results were obtained using heat flow numerical analysis, which included an optimization method specifically developed for this type of array. It was demonstrated that thermal optimization of a one-dimensional edge-emitting laser array can be achieved by adjusting the placement of the emitters within the array and the size of the top gold contact, without changing the overall dimensions of the device.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Nankai University, School of Materials Science and Engineering, CHINA.
The application of temperature-compensated photonic device is hampered by poor accuracy and overly simplistic functions of propagation in photonic integrated circuits (PICs) field. Herein, we report a new library of donor-acceptor metal-organic framework (D-A MOF) with thermally activated delayed fluorescence (TADF) and the fabricating of temperature-compensated photonic device by virtue of the unique temperature response character of TADF emitters. Highly tunable through-space charge transfer (TSCT) of TADF was realized within the D-A MOFs through a novel strategy that synergistically combines the internal heavy atom effect (HAE) with an external HAE, induced by the incorporation of heavy atoms into different components, achieving the regulable photophysical indicators including adjustable PL wavelength (534 to 592 nm) and surging quantum yield (5.
View Article and Find Full Text PDFACS Nano
January 2025
Institute of Functional Nano & Soft Materials (FUNSOM), Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123, Jiangsu, China.
Thermally activated delayed fluorescence (TADF) materials have received increasing attention from organic electronics to other related fields, such as bioapplications and photocatalysts. However, it remains a challenging task for TADF emitters to showcase the versatility concurrent with high performance in multiple applications. Herein, we first present such a proof-of-concept TADF material, namely, QCN-SAC, through strategically manipulating exciton dynamics.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Shandong Province Key Laboratory of Medical Physics and Image Processing Technology, School of Physics and Electronics, Shandong Normal University, Jinan 250014, China.
The strategy of designing efficient room-temperature phosphorescence (RTP) emitters based on hydrogen bond interactions has attracted great attention in recent years. However, the regulation mechanism of the hydrogen bond on the RTP property remains unclear, and corresponding theoretical investigations are highly desired. Herein, the structure-property relationship and the internal mechanism of the hydrogen bond effect in regulating the RTP property are studied through the combination of quantum mechanics and molecular mechanics methods (QM/MM) coupled with the thermal vibration correlation function method.
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