Interaction of Stabilized Alkylbenzene Sulfonate Surfactants on the Nanoscale with Water-Wet and Oil-Wet Carbonate Surfaces under High-Salinity and High-Temperature Conditions: A QCM-D Study.

Understanding the interactions of surfactants and wettability alteration of surfaces is important for many fields, including oil and gas recovery. This work utilizes the quartz crystal microbalance with dissipation to study the interaction of stabilized linear and branched alkylbenzene sulfonates (ABSs), among the most cost-efficient industrial surfactants, with water- and oil-wet calcite surfaces under high-salinity and high-temperature conditions. Confocal laser scanning microscopy is also used to study the effect of the type of ABS on their interaction with oil-wet calcite surfaces. Experiments demonstrate that vesicles made of linear and branched ABSs interact differently with both water- and oil-wet surfaces. Therefore, surfactant formulations made of ABSs for high-salinity applications can further be improved for advantageous wettability properties by varying the hydrophobic chain of the surfactants. When interacting with a water-wet surface, both types of vesicles adsorb onto the surface as is. Upon dilution, however, vesicles made of linear ABS stay adsorbed as is, and vesicles made of branched ABSs disassemble and produce a layered structure with altered wettability. Linear ABSs show greater efficiency in desorbing oil from the oil-wet calcite. The results of this study demonstrate an improved method for studying and understanding the interaction of surfactant formulations with water- and oil-wet surfaces. This approach could significantly benefit applications in which wettability alteration of surfaces is of great interest and facilitate the implementation of low-cost surfactants based on petroleum sulfonates.