Thermo/Anion Dual-Responsive Supramolecular Organoplatinum-Crown Ether Complex.

Org Lett

Department of Chemistry, University of Utah, 315 South 1400 East, Room 2020, Salt Lake City, Utah 84112, United States.

Published: June 2020

Stimuli-responsive complexes have attracted significant interest in supramolecular chemistry and material science. In this study, a new organoplatinum-crown supramolecular complex has been successfully constructed via the coordination of benzo-21-crown-7 () units and -Pt(PEt)(OTf). The resulting complex displays intriguing lower critical solution temperature (LCST) and anion-sensitive deassembly behavior. This organoplatinum-crown ether complex with dual-responsive behavior is a promising candidate for stimuli-responsive materials.

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Source
http://dx.doi.org/10.1021/acs.orglett.0c01333DOI Listing

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