Previous studies have demonstrated that SARS-CoV-2 is stable on surfaces for extended periods under indoor conditions. In the present study, simulated sunlight rapidly inactivated SARS-CoV-2 suspended in either simulated saliva or culture media and dried on stainless steel coupons. Ninety percent of infectious virus was inactivated every 6.8 minutes in simulated saliva and every 14.3 minutes in culture media when exposed to simulated sunlight representative of the summer solstice at 40°N latitude at sea level on a clear day. Significant inactivation also occurred, albeit at a slower rate, under lower simulated sunlight levels. The present study provides the first evidence that sunlight may rapidly inactivate SARS-CoV-2 on surfaces, suggesting that persistence, and subsequently exposure risk, may vary significantly between indoor and outdoor environments. Additionally, these data indicate that natural sunlight may be effective as a disinfectant for contaminated nonporous materials.
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http://dx.doi.org/10.1093/infdis/jiaa274 | DOI Listing |
J Phys Chem B
December 2024
Dipartimento di Biotecnologie, Chimica e Farmacia, Università degli Studi di Siena, Via A. Moro 2, Siena 53100, Italy.
The functional units of natural photosynthetic systems control the process of converting sunlight into chemical energy. In this article, we explore a series of chemically and structurally modified bacteriochlorophyll and chlorophyll pigments through computational chemistry to evaluate their electronic spectroscopy properties. More specifically, we use multiconfigurational and time-dependent density functional theory methods, along with molecular dynamics simulations, to compute the models' energetics both in an implicit and explicit solvent environment.
View Article and Find Full Text PDFLangmuir
December 2024
School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China.
To address the limitations of carbon nitride in photocatalysis, we propose constructing a three-dimensional interwoven SiC/g-CN composite structure. Utilizing the strong microwave-thermal conversion characteristics of SiC whiskers, localized "hot spots" are generated, which induce rapid thermal gradients, promoting rapid polymerization of urea and in situ formation of the interwoven network. This unique structure strengthens the interaction between these two components, creates multiple electron transport pathways, enhances CO adsorption, and effectively improves charge separation while reducing photogenerated carrier recombination.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China; Nanhai Institute of Harbin Engineering University, Sanya 572024, China. Electronic address:
The rational use of solar energy to achieve photothermal conversion is an attractive strategy to promote the efficient removal of radioactive Cs and Sr from nuclear wastewater. Herein, a photothermal adsorbent of composite aerogel with three-dimensional porous structure is fabricated by integrating prussian blue analogues (PBAs) and straw biochar into the chitosan (CS) and waste leather scrap hydrolysate (WLSH) aerogel matrix (CS/WLSH/C/PBAs). The local heating effect generated by CS/WLSH/C/PBAs aerogel induce to generate steam, accelerating the enrichment of Cs and Sr in the solution, which increase their interaction with the CS/WLSH/C/PBAs and improves their adsorption rates and capacities.
View Article and Find Full Text PDFChemosphere
December 2024
Département des sciences de la Terre et de l'atmosphère, Université du Québec à Montréal, Montréal, QC, H2X 1Y4, Canada; Geotop Research Centre, Montréal, QC, H2X 3Y7, Canada. Electronic address:
Many processes can contribute to the attenuation of the frequently detected and toxic herbicides atrazine and metolachlor in surface water, including photodegradation. Multi-element compound-specific isotope analysis has the potential to decipher between these different degradation pathways as Cl is a promising tool for both pathway identification and a sensitive indicator of degradation for both atrazine and metolachlor. In this study, photodegradation experiments of atrazine and metolachlor were conducted under simulated sunlight in buffered solutions (direct photodegradation) and with nitrate (indirect photodegradation by OH radicals) to determine kinetics, transformation products and isotope fractionation for C, N and for the first time Cl.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
ICCAS: Institute of Chemistry Chinese Academy of Sciences, ICCAS, ICCAS, CHINA.
Organic photovoltaic materials typically exhibit low charge separation and transfer efficiency and severe exciton/carrier recombination due to high exciton binding energy and short exciton diffusion lengths, limiting the enhancement of photocatalytic hydrogen evolution performance. Here, we introduce a surface charge reversal strategy to regulate charge characters of organic photovoltaic catalyst (OPC). Compared to OPC nanoparticles (NPs) stabilized by anionic surfactant ((-) NPs), NPs stabilized by cationic surfactant ((+) NPs) exhibit a raised Fermi level, larger surface band bending and Schottky barrier, thereby enhancing charge separation and transfer efficiency while suppressing charge carrier recombination.
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