Combined metal/air fuel cell and electrocoagulation process: Energy generation, flocs production and pollutant removal.

Electrocoagulation (EC) which is characterized by in-situ generation of highly absorbable hydroxide flocs, is an environmentally friendly process for treating heavy metal ions and toxic organic wastewater. In order to decrease EC's energy consumption, a combined metal/air FC-EC process which contains two successive parts: metal/air fuel cell (FC) and electrocoagulation (EC) was studied with the consideration of hydroxide flocs production, pollutant removal and energy generation analysis. For the combined iron/air FC-EC process, the porous nickel cathode which has a good performance in high polarization zone was selected as the ideal air cathode. It was found that iron/air FC-EC with acid electrolyte condition has a high energy generation (as high as 20% EC energy consumption). The energy generation increases with iron/air FC time. Also energy generation increases with wastewater's conductivity. Beside the energy generation, the iron/air fuel cell generate extra coagulants Fe for the subsequent EC process. The coagulants generated from iron/air FC and EC process together have further spontaneous hydrolysis reactions with the OH to form hydroxide flocs, which are beneficial for a rapid adsorption and pollutant trapping. Compared with EC process, iron/air (or Al/air) FC-EC process shows lower energy consumption and high removal efficiency for treating acid wastewater.