In this paper, we experimentally investigate the migration of liquid bridges at the interface of spheres and plates with an imposed thermal gradient. The key influencing factors of interface gap, sphere material and diameter, liquid viscosity, and thermal gradient on the migration behaviors are highlighted. Furthermore, the physical mechanism of this intriguing interfacial phenomenon is numerically unraveled. The originality of this work lies in the fact that when thermal gradients were encountered, liquid bridges could migrate at the interface of spheres and plates, and a general design philosophy of related parameters for enhancing or weakening this thermal flow is proposed.
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http://dx.doi.org/10.1021/acs.langmuir.9b03951 | DOI Listing |
J Colloid Interface Sci
December 2024
Department of Mechanical Engineering (Robotics), Guangdong Technion - Israel Institute of Technology, Shantou, Guangdong 515063, China.
Hypothesis: Current models for receding contact angles of Cassie-Baxter state droplets on textured hydrophobic substrates are applicable only to a specific structural type, e.g., pillar (above which a droplet has isolated contact line and continuous liquid-vapor interface) or pore (continuous contact line and isolated liquid-vapor interface), signifying a lack of universality.
View Article and Find Full Text PDFLangmuir
January 2025
Department of Mechanical Engineering, Indian Institute of Technology Guwahati, Guwahati 781039, India.
Understanding the droplet coalescence/merging is vital for many areas of microfluidics such as biochemical reactors, drug delivery, inkjet printing, oil recovery, etc. In the present study, we carried out numerical simulations of two magnetic droplets suspended in a nonmagnetic fluid matrix and coalescing under the influence of an external magnetic field. We observed that the applied magnetic field played a key role in the merging dynamics of the magnetic droplets.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Functional Materials and Electrochemistry Lab, Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur, West Bengal 721302, India.
The rational design and synthesis of bifunctionally active and durable oxygen electrocatalysts have garnered significant attention for electrochemical energy conversion and storage. Intermetallic nanostructures are particularly promising for these applications due to their unique catalytic properties and exceptional durability. In this study, we present a fascinating synthetic approach for the direct synthesis of a bifunctional oxygen electrocatalyst based on nitrogen-doped carbon-encapsulated ordered PdFe (o-PdFe@NC) intermetallic, using a cyano-bridged bimetallic single-source precursor tailored for aqueous rechargeable zinc-air batteries (ZABs).
View Article and Find Full Text PDFPrecis Chem
December 2024
State Key Laboratory of Physical Chemistry of Solid Surfaces, iChEM, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
The interfacial proton transfer (PT) reaction on the metal oxide surface is an important step in many chemical processes including photoelectrocatalytic water splitting, dehydrogenation, and hydrogen storage. The investigation of the PT process, in terms of thermodynamics and kinetics, has received considerable attention, but the individual free energy barriers and solvent effects for different PT pathways on rutile oxide are still lacking. Here, by applying a combination of ab initio and deep potential molecular dynamics methods, we have studied interfacial PT mechanisms by selecting the rutile SnO(110)/HO interface as an example of an oxide with the characteristic of frequently interfacial PT processes.
View Article and Find Full Text PDFToxins (Basel)
December 2024
Centre of Excellence in Mycotoxicology and Public Health, Department of Bioanalysis, Faculty of Pharmaceutical Sciences, Ghent University, B-9000 Ghent, Belgium.
Cheese is vulnerable to contamination with mycotoxins, particularly ochratoxin A (OTA) and aflatoxin M1 (AFM1). This study aims to develop and validate an analytical method for the detection and quantification of OTA and AFM1 in cheese and to assess their prevalence and associated risks. A liquid chromatography-tandem mass spectrometry (LC-MS/MS) method was validated for detecting these mycotoxins in 41 cheese samples, including firm-ripened, spreadable, and plant-based alternatives.
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