The global economy is threatened by the depletion of fossil resources and fluctuations in fossil fuel prices, and thus it is necessary to exploit sustainable energy sources. Carbon-neutral fuels including bio-oil obtained from biomass pyrolysis can act as alternatives to fossil fuels. Co-pyrolysis of lignocellulosic biomass and plastic is efficient to upgrade the quality of bio-oil because plastic facilitates deoxygenation. However, catalysts are required to produce bio-oil that is suitable for potential use as transportation fuel. This review presents an overview of recent advances in catalytic co-pyrolysis of biomass and plastic from the perspective of chemistry, catalyst, and feedstock pretreatment. Additionally, this review introduces not only recent research results of acid catalysts for catalytic co-pyrolysis, but also recent approaches that utilize base catalysts. Future research directions are suggested for commercially feasible co-pyrolysis process.
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http://dx.doi.org/10.1016/j.biortech.2020.123473 | DOI Listing |
PNAS Nexus
January 2025
CAS Key Laboratory of Urban Pollutant Conversion, Department of Environmental Science and Engineering, University of Science and Technology of China, Hefei 230026, China.
The relentless depletion of fossil fuels accentuates the urgent necessity for the sustainable synthesis of chemicals from renewable biomass. 5-Hydroxymethylfurfural (HMF), extracted from lignocellulosic biomass, emerges as a beacon of hope for conversion into value-added chemicals. However, the inherent susceptibility of its unsaturated aldehyde groups to excessive oxidation often culminates in undesired reactions, compromising both the yield and specificity of the desired products.
View Article and Find Full Text PDFJ Hazard Mater
November 2024
Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510630, China.
Effective management of antibiotic sludge (AS) is essential for disease prevention. This study investigated the co-pyrolysis of AS with polyurethane (PU) and rubber tires (RT), focusing on its key drivers, synergies, resulting products, and atmospheric (N versus CO) dependency. Composite pyrolysis index indicated superior co-pyrolysis properties of AS with PU or RT in the CO atmosphere compared with those in the N atmosphere.
View Article and Find Full Text PDFEnviron Res
January 2025
Department of Earth Resources and Environmental Engineering, Hanyang University, Seoul, 04763, Republic of Korea. Electronic address:
Antibiotics in aquatic environments can foster the development of antibiotic-resistant bacteria, posing significant risks to both living organisms and ecosystems. This study explored the thermo-chemical conversion of cattle manure (CM) into biochar and assessed its potential as an environmental medium for removing nitrofurantoin (NFT) from water. The biochar was produced through the co-pyrolysis of CM and acid mine drainage sludge (AMDS) in a N condition.
View Article and Find Full Text PDFEnviron Res
October 2023
Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600, UKM, Bangi, Selangor, Malaysia; Centre for Herbal Pharmacology and Environmental Sustainability, Chettinad Hospital and Research Institute, Chettinad Academy of Research and Education, Kelambakkam, 603103, Tamil Nadu, India. Electronic address:
Hierarchical designing of (10 wt% - 70 wt%) nickel over HZSM-5 zeolite was done using wet-impregnation method. The material formation was established by XRD, BET, TPD and TEM studies. Optimization of reaction parameters for mixture of LDPE derived oil and waste cooking oil was found to be 450 °C, 4.
View Article and Find Full Text PDFChemSusChem
October 2024
Center for Water and Ecology, State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, 100084, Beijing, China.
Homostructure construction has been proven to be an effective method for boosting the photocatalytic activity of polymeric carbon nitride. However, the contribution of the intrinsic activity of molecular fragments in the catalytic performance of homostructured carbon nitride is yet to be explored. In this paper, a facile hydrogen-assisted strategy was used to synthesize triazine/heptazine intermolecular homojunctions (g-CN(MU-H)) with an ultrathin and defective structure, via the co-pyrolysis of melamine and urea precursors.
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