In this study, corrosion-resistant composite coatings were produced by incorporating zinc (Zn) nanoparticles in an epoxy resin and a hybrid silicone resin. While performing sodium chloride saltspray tests, the corrosion performance of the nano-composite coatings was evaluated by applying these corrosion-resistant composite coatings on a carbon steel substrate. The nano-composite coatings on the substrates were characterized by an adhesion test, scanning electron microscope (SEM), and transmission electron microscope (TEM) with energy-dispersive X-ray spectroscopy (EDX). The results of the salt-spray tests showed that the Zn nanoparticles in the epoxy and hybrid silicone resins could react with permeated oxygen, thereby improving the anticorrosion properties of the Zn nano-composites. The corroded area of the epoxy resin samples decreased from more than 80% without Zn doping to less than 5% in a 3000-ppm Zn-doped sample after a 500-h saltspray test. An evaluation of the bactericidal properties showed that the Zn/epoxy and Zn/hybrid silicone resin nano-composites with at least 360 ppm of Zn nanoparticles exhibited bactericidal ability, which remarkably increased with the Zn nanoparticles content. The corrosion-resistant properties improved with the addition of Zn nano-composites coatings.
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http://dx.doi.org/10.1166/jnn.2020.18709 | DOI Listing |
Langmuir
January 2025
College of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
Nanocomposites of epoxy with FeO featuring dynamic disulfide bonds were fabricated. To facilitate the dispersion of FeO nanoparticles, we synthesized poly(ε-caprolactone)-grafted FeO nanoparticles, which were then incorporated into epoxy to generate robust interfacial interactions between epoxy and the inorganic nanoparticles. Through this approach, a fine dispersion of the inorganic nanoparticles in the epoxy matrix was successfully obtained.
View Article and Find Full Text PDFHeliyon
January 2025
Department of Physics, College of Science, De La Salle University, Philippines.
Exposure to mid-energy radiation poses significant health risks, necessitating the development of effective shielding materials. Traditional lead-based shields, while effective, have significant drawbacks including toxicity and environmental concerns. This study investigates the potential of lead-free epoxy resin nanocomposites, incorporating bismuth oxide, nickel oxide, and cerium oxide, for mid-energy radiation protection.
View Article and Find Full Text PDFLangmuir
January 2025
State Key Laboratory for Environment-Friendly Energy Materials, School of Materials and Chemistry, Southwest University of Science and Technology, Mianyang 621010, China.
To achieve superhydrophobicity with an apparent contact angle (θ*) greater than 150° on rough surfaces, materials with a high Young's contact angle (θ > 90°) are commonly utilized. However, achieving superhydrophobicity with θ < 90° materials without specific auxiliary designs faces unknown challenges. Here, we develop a novel superhydrophobic nanocoating with θ* of ∼155° sprayed by an ethanol suspension only composed of bisphenol A epoxy resin (EPA) with a low θ of ∼70° and hydrophilic SiO nanoparticles.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science & Technology, Qingdao, 266042, China. Electronic address:
Wearable microneedle array (MNA) based electrochemical sensors have gained increasing attention for their capability to analyze biomarkers in the interstitial fluid (ISF), enabling noninvasive, continuous monitoring of health parameters. However, challenges such as nonspecific adsorption of biomolecules on the sensor surfaces and the risk of infection at the microneedle penetration sites hinder their practical application. Herein, a wearable dual-layer microneedle patch was prepared to overcome these issues by integrating an antimicrobial microneedle layer with an antifouling sensing layer.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Chemistry, University of Zanjan, Zanjan, Iran. Electronic address:
The catalytic performance of Candida antarctica lipase B (CALB) immobilized on silica-coated magnetic nanoparticles was evaluated for biodiesel production via methanolysis of rapeseed oil. Two different covalent immobilization approaches were compared to assess the effect of immobilization protocols on lipase efficiency. The first approach involved immobilization of CALB on amine-functionalized magnetic nanoparticles (MNPs), which targeted the Lys-rich regions of the enzyme.
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