We analyze the fluctuations in particle positions and interparticle forces in disordered crystals composed of jammed soft particles in the limit of weak disorder. We demonstrate that such athermal systems are fundamentally different from their thermal counterparts, characterized by constrained fluctuations of forces perpendicular to the lattice directions. We develop a disorder perturbation expansion in polydispersity about the crystalline state, which we use to derive exact results to linear order. We show that constrained fluctuations result as a consequence of local force balance conditions, and are characterized by non-Gaussian distributions, which we derive exactly. We analytically predict several properties of such systems, including the scaling of the average coordination with polydispersity and packing fraction, which we verify with numerical simulations using soft disks with one-sided harmonic interactions.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevLett.124.168004 | DOI Listing |
Phys Chem Chem Phys
January 2025
State Key Lab of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
Mechanoresponsive colloidal photonic crystals embedded in elastic solid matrices exhibit tunable optical properties under mechanical force, showing great potential for various applications. However, the response of colloidal crystals embedded in a liquid matrix remains largely unexplored. In this study, we investigate the structural and optical transitions of colloidal crystals composed of particles suspended in a liquid oligomer under pressing and shear forces.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Fuzhou University College of Chemical Engineering, College of Chemical Engineering, CHINA.
Polyethylene oxide (PEO)-based electrolytes are essential to advance all-solid-state lithium batteries (ASSLBs) with high safety/energy density due to their inherent flexibility and scalability. However, the inefficient Li+ transport in PEO often leads to poor rate performance and diminished stability of the ASSLBs. The regulation of intermolecular H-bonds is regarded as one of the most effective approaches to enable efficient Li+ transport, while the practical performances are hindered by the electrochemical instability of free H-bond donors and the constrained mobility of highly ordered H-bonding structures.
View Article and Find Full Text PDFMolecules
January 2025
Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China.
Rare earth phosphate (XPO) is an extremely important rare earth compound. It can exhibit excellent activity and stability in catalytic applications by modifying its inherent properties. Porous single-crystalline (PSC) PrPO and SmPO with a large surface area consist of ordered lattices and disordered interconnected pores, resulting in activity similar to nanocrystals and stability resembling bulk crystals.
View Article and Find Full Text PDFACS Nano
January 2025
School of Materials Science and Engineering, Peking University, Beijing 100871, People's Republic of China.
Single-crystal Au(111), renowned for its chemically inert surface, long-range "herringbone" reconstruction, and high electrical conductivity, has long served as an exemplary template in diverse fields, , crystal epitaxy, electronics, and electrocatalysis. However, commercial Au(111) products are high-priced and limited to centimeter sizes, largely restricting their broad applications. Herein, a low-cost, high-reproducible method is developed to produce 4 in.
View Article and Find Full Text PDFSoft Matter
January 2025
Department of Physics, Government College of Engineering and Textile Technology, 12 William Carey Road, Serampore, Hooghly-712201, India.
The theoretical study of instabilities, thermal fluctuations, and topological defects in the crystal-rotator-I-rotator-II (X-R-R) phase transitions of -alkanes has been conducted. First, we examine the nature of the R-R phase transition in nanoconfined alkanes. We propose that under confined conditions, the presence of quenched random orientational disorder makes the R phase unstable.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!