Structural characterization of molybdenum-dinitrogen complex as key species toward ammonia formation by dispersive XAFS spectroscopy.

Phys Chem Chem Phys

Department of Interdisciplinary Environment, Graduate School of Human and Environmental Studies, Kyoto University, Yoshida Nihonmatsu-cho, Sakyo-ku, Kyoto 606-8501, Japan.

Published: June 2020

The structural characterization of a hardly-isolatable molybdenum-dinitrogen complex bearing a PNP-type pincer ligand, which is assumed to be a key reactive complex in the stoichiometric transformation of a molybdenum triiodide complex [MoI(PNP)] into the corresponding molybdenum nitride complex under an atmospheric pressure of dinitrogen, was carried out by using dispersive XAFS.

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Source
http://dx.doi.org/10.1039/c9cp06761bDOI Listing

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