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The solvent extraction of gold, palladium, technetium, indium and rhenium from both mixtures of a deep eutectic solvent with aqueous salt solutions and of two different aqueous salt solutions has been performed. Initially using gold and then the other metals the solvent extraction results were interpreted using an activity coefficient/function equation (specific ion interaction theory). The most important presented result is the addition of a new term to the specific ion interaction theory equation. Using the new model it will be possible to make predictions of the behaviour of a solvent extraction system where one of the liquid phases is a mixture of aqueous salts and the deep eutectic solvent.
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http://dx.doi.org/10.1039/c9cp05982b | DOI Listing |
Prep Biochem Biotechnol
December 2024
Department of Chemical Engineering, Institute of Chemical Technology (ICT), Mumbai, India.
With numerous advantages over conventional techniques, ultrasound-assisted extraction (UAE) has become a viable method for the effective extraction of biomolecules from prokaryotic and eukaryotic cells. The fundamentals and workings of UAE are examined in this review, focusing on current developments, including how these impact the extraction of proteins, lipids, enzymes, and other bioactive compounds. UAE not only enhances cell disruption and mass transfer, leading to improved extraction yields, but also preserves the integrity of the extracted bioactive molecules under optimized conditions, making it a preferred choice in Biochemistry and Biotechnology.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Poznan University of Technology, Berdychowo 4, Poznan, 60965, Poland.
Porous deep eutectic solvents (PDES) are capturing the imagination of scientists, promising a revolutionary leap in material science. These innovative materials, blending the versatility of deep eutectic solvents (DES) with the intricate architectures of porous structures, offer an exciting array of applications-from green chemistry and catalysis to energy storage and environmental remediation. However, the journey from laboratory curiosity to industrial application is fraught with challenges.
View Article and Find Full Text PDFJ Sep Sci
December 2024
Departamento de Química, Universidade Federal de Santa Catarina, Florianopolis, Brazil.
This study introduces a green approach to sample preparation by applying natural deep eutectic solvents (NADES) to determine phthalates in carbonated soft drinks using high-performance liquid chromatography with diode array detector (HPLC-DAD). The method employs hollow fiber-microporous membrane liquid-liquid microextraction combined with a 96-well plate system, utilizing fatty-acid-based DES in the pores of the membranes. This methodology substantially reduces the use of organic solvents, and its efficiency is comparable to or better than conventional methods.
View Article and Find Full Text PDFChemSusChem
December 2024
Universita degli Studi Magna Graecia di Catanzaro, Dipartimento di Scienze della Salute, ITALY.
In this paper, Krapcho's one-step decarbomethoxylation of oleuropein in DES is reported. Oleuropein used as reagent was extracted with water from olive leaves, widely available and inexpensive waste from the olive oil production chain. The reaction has been carried out in a series of ChCl-based DES of increasing acidity, with or without the addition of an amount of water, under microwave and conventional heating.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Central South University, School of Metallurgy and Environment, CHINA.
The recycling of critical metals from spent lithium-ion batteries represents a significant step towards meeting the enhancing resource requirements in the new energy industry. Nevertheless, achieving effective leaching of metals from the stable metal-oxygen (MO6) structure of spent ternary cathodes and separation of metal products simultaneously still remained a huge challenge towards industrial applications. Herein, a competitive coordination strategy was proposed to design a novel deep eutectic solvent (DESs), which improved both leaching and selective metal recycling capacity even at high solid-liquid ratio (1:10).
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