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A new approach to the synthesis of trinuclear gold(i) imidazolate complexes and their silver(i)-induced photoluminescence behavior. | LitMetric
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A new approach to the synthesis of trinuclear gold(i) imidazolate complexes and their silver(i)-induced photoluminescence behavior.

Javier Ruiz Daniel Sol María A Mateo Marilín Vivanco Rosana Badía-Laiño

Dalton Trans

Departamento de Química Física y Analítica, Facultad de Química, Universidad de Oviedo, 33006 Oviedo, Spain.

Published: May 2020

New trinuclear gold(i) N-arylimidazolate cluster complexes have been synthesized from cationic [Au(CNR)2]+ isocyanide complexes and their structure and photoluminescence behavior have been compared with those of their 1-methylimidazolate counterpart. A drastic change in their photophysical properties was observed upon coordination of the Ag+ cation.

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http://dx.doi.org/10.1039/d0dt01246gDOI Listing

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