Pressure-Assisted Fabrication of Perovskite Solar Cells.

Sci Rep

Department of Mechanical Engineering, Worcester Polytechnic Institute, 100 Institute Road, Worcester, MA, 01609, USA.

Published: April 2020

This paper presents the results of a combined experimental and analytical/computational study of the effects of pressure on photoconversion efficiencies of perovskite solar cells (PSCs). First, an analytical model is used to predict the effects of pressure on interfacial contact in the multilayered structures of PSCs. The PSCs are then fabricated before applying a range of pressures to the devices to improve their interfacial surface contacts. The results show that the photoconversion efficiencies of PSCs increase by ~40%, for applied pressures between 0 and ~7 MPa. However, the photoconversion efficiencies decrease with increasing pressure beyond ~7 MPa. The implications of the results are discussed for the fabrication of efficient PSCs.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7188881PMC
http://dx.doi.org/10.1038/s41598-020-64090-5DOI Listing

Publication Analysis

Top Keywords

photoconversion efficiencies
12
perovskite solar
8
solar cells
8
effects pressure
8
pscs
5
pressure-assisted fabrication
4
fabrication perovskite
4
cells paper
4
paper presents
4
presents combined
4

Similar Publications

To advance off-grid energy solutions, developing flexible photobatteries capable of direct light charging is essential. This study presents an innovative photobattery architecture that incorporates zinc oxide (ZnO) as an electron-transporting and hole-blocking layer, combined with a hybrid methylammonium tin iodide composite with poly-triarylamine (MASnI/PTAA) for light absorption and hole transport. PTAA facilitates efficient hole transport to the anode, thereby enhancing charge separation and reducing recombination losses.

View Article and Find Full Text PDF

Doping and surface-modification are well-established strategies for the performance enhancement of bismuth vanadate (BiVO) photoanodes in photoelectrochemical (PEC) water splitting devices. Herein, a "double-use" strategy for the development of high-performance BiVO photoanodes for solar water splitting is reported, where a molecular cobalt-phosphotungstate (CoPOM = Na[Co(HO)(PWO)]) is used both as a bulk doping agent as well as a surface-deposited water oxidation cocatalyst. The use of CoPOM for bulk doping of BiVO is shown to enhance the electrical conductivity and improve the charge separation efficiency, resulting in the enhancement of the maximum applied-bias photoconversion efficiency (ABPE) by a factor of ∼18 to 0.

View Article and Find Full Text PDF

Photoswitches are widely investigated molecules because upon exposure to selected light irradiation, they are able to undergo structural, and hence optical, changes. To fully exploit their responsiveness to irradiation, the quantum efficiency of the forward and back reactions is a fundamental parameter, whose accurate determination is critical. In this work, the spectral evolution of a biomimetic switch, which undergoes / photoinduced isomerization, is spectrophotometrically examined.

View Article and Find Full Text PDF

Lead halide perovskites demonstrate outstanding luminescent characteristics. However, the inclusion of lead components restricts their extensive utilization. Halide perovskite materials, formulated as AM(III)M(I)X or AM(IV)X, possess the potential to serve as stable and eco-friendly substitutes for optoelectronic applications.

View Article and Find Full Text PDF
Article Synopsis
  • Quantum dots with a semiconductor-core and metal-shell structure can be tuned for better photo-electrical properties by adjusting their core and shell parameters.
  • The study explored how adding a Mn-shell to Ge quantum dots in an alumina matrix affected their properties, demonstrating a successful formation of orderly arranged quantum dots through self-assembly.
  • Key findings indicated that the Mn shell significantly improved the optical gap and conductivity of the materials, leading to over a 100% enhancement in quantum efficiency due to multiple exciton generation, particularly when the shell was thin, highlighting their potential for use in photo-sensitive devices.
View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!