This paper presents the results of a combined experimental and analytical/computational study of the effects of pressure on photoconversion efficiencies of perovskite solar cells (PSCs). First, an analytical model is used to predict the effects of pressure on interfacial contact in the multilayered structures of PSCs. The PSCs are then fabricated before applying a range of pressures to the devices to improve their interfacial surface contacts. The results show that the photoconversion efficiencies of PSCs increase by ~40%, for applied pressures between 0 and ~7 MPa. However, the photoconversion efficiencies decrease with increasing pressure beyond ~7 MPa. The implications of the results are discussed for the fabrication of efficient PSCs.
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http://dx.doi.org/10.1038/s41598-020-64090-5 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Department of Physics, Riphah International University, Campus Lahore, Lahore 54000, Pakistan.
To advance off-grid energy solutions, developing flexible photobatteries capable of direct light charging is essential. This study presents an innovative photobattery architecture that incorporates zinc oxide (ZnO) as an electron-transporting and hole-blocking layer, combined with a hybrid methylammonium tin iodide composite with poly-triarylamine (MASnI/PTAA) for light absorption and hole transport. PTAA facilitates efficient hole transport to the anode, thereby enhancing charge separation and reducing recombination losses.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Institute of Electrochemistry, Ulm University, Albert-Einstein-Allee 47, Ulm 89081, Germany.
Doping and surface-modification are well-established strategies for the performance enhancement of bismuth vanadate (BiVO) photoanodes in photoelectrochemical (PEC) water splitting devices. Herein, a "double-use" strategy for the development of high-performance BiVO photoanodes for solar water splitting is reported, where a molecular cobalt-phosphotungstate (CoPOM = Na[Co(HO)(PWO)]) is used both as a bulk doping agent as well as a surface-deposited water oxidation cocatalyst. The use of CoPOM for bulk doping of BiVO is shown to enhance the electrical conductivity and improve the charge separation efficiency, resulting in the enhancement of the maximum applied-bias photoconversion efficiency (ABPE) by a factor of ∼18 to 0.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
Dipartimento di Chimica, Biologia e Biotecnologie, Università di Perugia, Via Elce di Sotto, 8, 06123 Perugia, Italy.
Photoswitches are widely investigated molecules because upon exposure to selected light irradiation, they are able to undergo structural, and hence optical, changes. To fully exploit their responsiveness to irradiation, the quantum efficiency of the forward and back reactions is a fundamental parameter, whose accurate determination is critical. In this work, the spectral evolution of a biomimetic switch, which undergoes / photoinduced isomerization, is spectrophotometrically examined.
View Article and Find Full Text PDFSmall
December 2024
State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing, 100029, China.
Lead halide perovskites demonstrate outstanding luminescent characteristics. However, the inclusion of lead components restricts their extensive utilization. Halide perovskite materials, formulated as AM(III)M(I)X or AM(IV)X, possess the potential to serve as stable and eco-friendly substitutes for optoelectronic applications.
View Article and Find Full Text PDFNanomaterials (Basel)
November 2024
Ruđer Bošković Institute, Bijenička Cesta 54, 10000 Zagreb, Croatia.
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