Using silicone rubber and polyvinylchloride as equilibrium passive samplers for rapid and sensitive monitoring of pyrethroid insecticides in aquatic environments.

Passive sampling to regularly identify the occurrence of pyrethroid insecticides in urban streams is a crucial work of risk management with respect to intrinsic toxicity of pyrethroids to aquatic organisms. Polymeric films, based on an equilibrium sampling principle, have found increasing use as passive samplers for hydrophobic contaminants. Herein, we investigated two thin-film samplers, namely silicone rubber (SR) and polyvinylchloride (PVC), compatible with a suite of 8 pyrethroids, for measuring freely dissolved concentrations (C) in water. The characteristics of SR and PVC samplers were estimated in terms of equilibrium partitioning coefficients (K) with log units of 3.90-4.67 and sampling rates (R) of 0.011-0.016 L/h. The parameters were correlated positively with octanol-water partition coefficients of the compounds, whereas independent on water solubility. A strong agreement between C obtained from the two samplers was observed in a range of 0.1-10 μg/L for pyrethroids under laboratory simulated conditions. Both of SR and PVC were confirmed as equilibrium samplers with faster sampling rates of pyrethroids that equilibrated on films within only one week, and higher accumulation at factors of 5.3-12.5 and 1.5-2.4 compared to a performance reference compound (PRC)-preload sampler. Additionally, the comparable results of the two passive sampling methods in multiple field applications indicated that the direct deployment of the two samplers without PRCs calibration can provide reliable assessment of trace concentrations. This study demonstrated the routine utilization of SR and PVC as promising tools for rapid and sensitive in-situ monitoring of pyrethroids, and indicators for the bioavailability against total chemical concentrations in variable aquatic environments.