Chrome tanning remains the most favourite technology in the leather industry worldwide due to its ability to produce leather with attributes desirable for high-quality leather such as excellent hydrothermal stability, better dyeing characteristics and softness. Nevertheless, the technology has been censured globally for its severe environmental detriments and adverse effects on human health and other organisms. Developing alternative eco-friendly tanning technologies capable of producing leather of high quality has remained a challenging scientific inquiry. This review article provides an assessment of various eco-friendly tanning attempts geared towards improving or replacing the chrome technology without compromising the quality of the produced leather. The reviewed publications have ascertained that, these attempts have been centred on recycling of spent liquors; chromium exhaustion enhancement and total replacement of chromium salts. The research gaps and levels of key environmental pollutants from the reviewed technologies are presented, and the qualities of the leather produced from these technologies are highlighted. Of all the examined alternative technologies, total replacement of chromium salts sounds ideal to elude adverse effects associated with chrome tanning. Combination tanning, which implies blending two tanning agents that individually cannot impart desired properties to the leather, is anticipated to be an alternative technology to chrome tanning. Apart from being an eco-friendly technology, combination tanning produces leather with similar features to those produced by chrome tanning. In this regard, blending vegetable tannins with aluminium sulphate provides a promising chrome-free tanning technology. However, further studies to optimize combination tanning technologies to suit industrial applications are highly recommended.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1016/j.chemosphere.2020.126804 | DOI Listing |
Environ Sci Pollut Res Int
December 2024
Sant'Anna School of Advanced Studies, Institute of Management, Piazza Martiri Della Libertà 33, 56127, Pisa, Italy.
Environ Sci Pollut Res Int
December 2024
Inorganic and Physical Chemistry Department, CSIR - Central Leather Research Institute (CLRI), Chennai, Tamil Nadu, India, 600020.
To overcome the stringent regulations in the usage of chromium salts and dye-rich effluent let out by the tanning industry, a sustainable way of leather processing has been demonstrated utilizing amine pendant metal-organic frameworks (MOF) UiO-66-NH along with glyoxal. It was found that an offer of 8% (w/w) MOF along with 6% (w/w) glyoxal increased the shrinkage temperature of the leathers to 89 ± 2 °C with exhaustion of MOF up to 84.3 ± 1.
View Article and Find Full Text PDFHeliyon
July 2024
Manufacturing Industry Development Institute, Leather and Leather Products Industry Research and Development Center, P.O. Box 24692 Code 1000, Addis Ababa, Ethiopia.
Hair burning unhairing and dampening of tannery wastes during the hair-saving unhairing process are becoming significant problems in the tanning industry. Therefore, this research article focuses on the extraction of keratin hydrolysate (KH) and its application as a chrome exhaust aid and keratin filler in leather manufacturing process. The structure, morphology and functional groups of the extract were examined using X-Ray Diffractometer (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectrometer (FTIR), respectively.
View Article and Find Full Text PDFJ Environ Manage
August 2024
College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi'an, 710021, Shaanxi, China. Electronic address:
The leather manufacturing industry is increasingly embracing chrome-free tanning methods to promote environmental sustainability. However, the transition to chrome-free tanning systems presents a notable obstacle: the incompatibility of traditional anionic wet finishing materials with chrome-free tanned leather due to differences in surface electrical behavior. Herein, an amphoteric polymer, referred to P(AA-co-DMAEMA-co-DA), was synthesized through a simple one-step free radical copolymerization using acrylic acid (AA), dimethylaminoethyl methacrylate (DMAEMA), and dodecyl acrylate (DA).
View Article and Find Full Text PDFSustain Chem Environ
June 2024
Institute of Leather Engineering and Technology, University of Dhaka, Dhaka 1209, Bangladesh.
Untreated tannery wastewater contains a large amount of toxic metals, dyes, and other pollutants, which pose adverse effects on the ecosystem and public health. In this work, a calcium alginate-poly vinyl alcohol-graphene oxide (CA-PVA-GO) composite was prepared to remove metals and dyes, particularly Cr(Ⅲ) and CI acid violet 54 (AV54) dye, from tannery wastewater. FESEM, FTIR, and XRD analyses were applied to characterize the GO and CA-PVA-GO.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!