Stable silver nanoparticles (AgNPs) of size 80 ± 11 nm produced by chitosan (CH) mediated green synthesis were blended with polyvinyl alcohol (PVA) to form electrospun fibrous composite nano-layers (FCNLs). The chitosan acted as the stabilising as well as an antimicrobial agent in combination with the AgNPs which were characterised using UV-visible spectrophotometry, dynamic light scattering (DLS) and scanning electron microscopy (SEM). The crystallinity and chemical nature of the electrospun composite was characterised by using X-ray diffraction (XRD) and FTIR spectroscopy, respectively, and its hydrophobicity was characterised by measuring the water contact angle. The electrospun composite showed effective antimicrobial activity against Listeria monocytogenes (gram +ve) and Escherichia coli (gram -ve) bacterial species. The electrospun composite, when tested as packaging material for meat, showed bio-activity and extended the meat shelf-life by one week. The electrospun nanocomposite is able to inhibit microbial degradation of packaged food and extend its keeping quality in an eco-friendly manner.
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http://dx.doi.org/10.1016/j.ijbiomac.2020.04.149 | DOI Listing |
ACS Appl Bio Mater
January 2025
Department of Physical Chemistry, Institute of Chemistry, Faculty of Chemistry and Geosciences, Vilnius University, Naugarduko Str. 24, LT-03225 Vilnius, Lithuania.
Electrospinning, a technique for creating fabric materials from polymer solutions, is widely used in various fields, including biomedicine. The unique properties of electrospun fibrous membranes, such as large surface area, compositional versatility, and customizable porous structure, make them ideal for advanced biomedical applications like tissue engineering and wound healing. By considering the high biocompatibility and well-known regenerative potential of polylactic acid (PLA) and chitosan (CH), as well as the versatile antibacterial effect of silver nanoparticles (AgNPs), this study explores the antibacterial efficacy, adhesive properties, and cytotoxicity of electrospun chitosan membranes with a unique nanofibrous structure and varying concentrations of AgNPs.
View Article and Find Full Text PDFSci Rep
January 2025
Chemistry Department, Faculty of Science, Menoufia University, Shibin El-Kom, 32511, Egypt.
In this work, microalgae-based zinc oxide nanoparticles loaded with electrospun polyvinyl alcohol (PVA)/sodium alginate (SA) nanofibers were fabricated by electro-spinner. PVA/SA fibrous mats were crosslinked by citric acid, which enhanced their thermal stability and swelling behavior. Green-synthesized ZnO NPs were laboratory synthesized and characterized by FTIR, XRD, EDX, SEM, TEM and TGA analyses.
View Article and Find Full Text PDFMacromol Rapid Commun
January 2025
UCL School of Pharmacy, University College London, 29-39 Brunswick Square, London, WC1N 1AX, UK.
Antimicrobial resistance poses a growing threat to public health globally. Multidrug resistant Pseudomonas (P.) aeruginosa is detected in many infected wounds and is very challenging to treat with antibiotics.
View Article and Find Full Text PDFFoods
January 2025
Center of Excellence Polymer Processing, Faculty of Engineering, Dunarea de Jos University of Galați, Domnească Street, No. 111, 800201 Galați, Romania.
Electrospinning is a versatile technique for obtaining nano/micro fibers which are able to significantly change the active properties of composite materials and bring in new dimensions to agri-food applications. Composite bio-based packaging materials obtained from whey proteins, functionalized with thyme essential oil (TEO) and reinforced by electrospun polylactic acid (PLA) fibers, represent a promising solution for developing new active food packaging using environmentally friendly materials. The aim of this study is to obtain and characterize one-side-active composite films covered with a PLA fiber mat: (i) WF/G1, WF/G2, and WF/G3 resulting from electrospinning with one needle at different electrospinning times of 90, 150, and 210 min, respectively, and (ii) WF/G4 obtained with two face-to-face needles after 210 min of electrospinning.
View Article and Find Full Text PDFInt J Mol Sci
December 2024
Department of Chemical Engineering, Barcelona East School of Engineering (EEBE), Polytechnic University of Catalonia, Av. Eduard Maristany, 10-14, Ed. I2, 08019 Barcelona, Spain.
This study explores the characterization and application of poly(3-hydroxybutyrate--3-hydroxyvalerate) (PHBV) synthesized from organic residues, specifically milk and molasses. Six PHBV samples with varying 3-hydroxyvalerate (3HV) content (7%, 15%, and 32%) were analyzed to assess how 3HV composition influences their properties. Comprehensive characterization techniques, including NMR, FTIR, XRD, DSC, TGA, and tensile-stress test, were used to evaluate the molecular structure, thermal properties, crystalline structure, and mechanical behavior.
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