Spatial distribution and source identification together with environmental health risk assessment of PAHs along the coastal zones of the USA.

Identification of polycyclic aromatic hydrocarbons (PAHs) sources and hot spot areas are the primary driving forces for their control in the environment. This study was performed in the US coastal areas to identify the major sources of PAHs and investigate the spatial distribution associated with carcinogenic PAHs (CPAHs) using a novel spatial forecasting method for the first time in environmental sciences. Diagnostic ratios of PAHs demonstrated the predominance of pyrogenic sources compared to petrogenic sources within the area of study. Five factors were extracted using positive matrix factorization method with respect to 16 priority PAHs, indicating the dominance of pyrogenic versus petrogenic sources mainly as a result of combustion products in the environment. The total toxic benzo[a]pyrene equivalency (TEQ) for all CPAHs ranged from 0.03 to 10,456 ng/g containing a mean of 199 ng/g. The contribution of each CPAH to the total TEQ varied according to the following order: benzo[a]pyrene (65.4%), dibenzo[a,h]anthracene (12%), benzo[b]fluoranthene (10%), benzo[a]anthracene (6%), indeno[1,2,3-c,d]pyrene (6%), benzo[k]fluoranthene (0.5%) and chrysene (0.1%). The spatial analysis by fixed rank kriging (FRK) highlighted a similar pattern associated with all of the CPAHs with higher values in the northern part of New Jersey State. In particular, Passaic River, Upper New York/New Jersey Harbor, Mullica River, Schuylkill River, Newark Bay and Christina River were the most contaminated stations regarding the observed values of CPAHs.