Collective excitation of periodic arrays of metallic nanoparticles by coupling localized surface plasmon resonances to grazing diffraction orders leads to surface lattice resonances with narrow line width. These resonances may find numerous applications in optical sensing and information processing. Here, a new degree of freedom of surface lattice resonances is experimentally investigated by demonstrating handedness-dependent excitation of surface lattice resonances in arrays of chiral plasmonic crescents. The self-assembly of particles used as mask and modified colloidal lithography is applied to produce arrays of planar and 3D gold crescents over large areas. The excitation of surface lattice resonances as a function of the interparticle distance and the degree of order within the arrays is investigated. The chirality of the individual 3D crescents leads to the formation of chiral lattice modes, that is, surface lattice resonances that exhibit optical activity.
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http://dx.doi.org/10.1002/adma.202001330 | DOI Listing |
Sci Adv
January 2025
Laboratoire de Physique des Solides, Université Paris-Saclay, CNRS, 91405 Orsay, France.
Charge transport in materials has an impact on a wide range of devices based on semiconductor, battery, or superconductor technology. Charge transport in sliding charge density waves (CDW) differs from all others in that the atomic lattice is directly involved in the transport process. To obtain an overall picture of the structural changes associated to the collective transport, the large coherent x-ray beam generated by an x-ray free-electron laser (XFEL) source was used.
View Article and Find Full Text PDFChaos
January 2025
Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306, USA.
Traveling waves of excitation arise from the spatial coupling of local nonlinear events by transport processes. In corrosion systems, these electro-dissolution waves relay local perturbations across large portions of the metal surface, significantly amplifying overall damage. For the example of the magnesium alloy AZ31B exposed to sodium chloride solution, we report experimental results suggesting the existence of a vulnerable zone in the wake of corrosion waves where local perturbations can induce a unidirectional wave pulse or segment.
View Article and Find Full Text PDFACS Nano
January 2025
Graduate Institute of Ferrous & Eco Materials Technology (GIFT), Pohang University of Science and Technology University, Pohang 37666, Republic of Korea.
Lattice volume changes in Li-ion batteries active materials are unavoidable during electrochemical cycling, posing significant engineering challenges from the particle to the electrode level. In this study, we present an elastic framework coating designed to absorb and reversibly release strain energy associated with particle volume changes, thereby enhancing mechanical resilience at both the particle and electrode levels. This framework, composed of multiwalled carbon nanotubes (MWCNTs), is applied to nickel-rich LiNiCoMnO (NCM9055) cathodes at a low loading of 0.
View Article and Find Full Text PDFNano Lett
January 2025
School of Physics and Key Laboratory of Functional Polymer Materials of Ministry of Education, Nankai University, and Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300071, China.
The structural properties of packed soft-core particles provide a platform to understand the cross-pollinated physical concepts in solid-state and soft-matter physics. Confined on a spherical surface, the traditional differential geometry also dictates the overall defect properties in otherwise regular crystal lattices. Using molecular dynamics simulation of the Hertzian model as a tool, we report here the emergence of new types of disclination patterns: domain and counter-domain defects, when hexagonal and square patterns coexist.
View Article and Find Full Text PDFInorg Chem
January 2025
Institute of Low Temperature and Structure Research, PAS, Okolna 2, 50-422 Wroclaw, Poland.
This paper discusses the origin of emission quenching in yttrium orthovanadate codoped with Eu and Sb ions. Highly crystalline yttrium orthovanadate nanoparticles with chemical composition YEuSbVO ( = 0-5.4 mol %, = 0-2.
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