Human activities and population growth have increased the natural burden of reactive nitrogen (N) in the environment. Excessive N deposition on Earth's surface leads to adverse feedbacks on ecosystems and humans. Similar to that of air pollution, emission control is recognized as an efficient means to control acid deposition. Control of nitrogen oxides (NO = NO + NO) emissions has led to reduction in deposition of oxidized nitrogen (NO, the sum of all oxidized nitrogen species, except nitrous oxide [NO]). Reduced forms of nitrogen (NH = ammonia [NH] + ammonium [NH]) deposition have, otherwise, increased, offsetting the benefit of reduction in NO deposition. Stringent control of NH emissions is being considered. In this study, we assess the response of N deposition to N emission control on continental regions. We show that significant reduction of NH deposition is unlikely to be achieved at the early stages of implementing NH emission abatement. Per-unit NH emission abatement is shown to result in only 60-80% reduction in NH deposition, which is significantly lower than the demonstrated 80-120% benefit of controlling NO emissions on NO deposition. This 60-80% effectiveness of NH deposition reduction per unit NH emission abatement reflects, in part, the effects of simultaneous reductions in NO and SO emissions.
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http://dx.doi.org/10.1073/pnas.1920068117 | DOI Listing |
Sci Total Environ
January 2025
The University of Yaoundé I, National Advanced School of Engineering of Yaoundé, P.O. Box: 8390, Yaoundé, Cameroon. Electronic address:
Carbon dioxide (CO) accumulation and emission are well-known features of deep lakes, making them a significant unavoidable carbon source to the atmosphere. In the case of meromictic lakes, degassing devices are installed to controllably release through a pipe the CO trapped in the bottom waters. Otherwise, the gas is emitted diffusely at the air-water surface or accidentally through a limnic eruption when the saturation limit is reached.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.
Ammonia emissions from vehicles and power plants cause severe environmental issues, including haze pollution and nitrogen deposition. Selective catalytic oxidation (SCO) is a promising technology for ammonia abatement, but current catalysts often struggle with insufficient activity and poor nitrogen selectivity, leading to the formation of secondary pollutants. In this study, we developed a bifunctional Ru/Cu-CHA zeolite catalyst for ammonia oxidation, incorporating both SCO sites (Ru) and selective catalytic reduction sites (SCR, Cu).
View Article and Find Full Text PDFSci Total Environ
January 2025
School of the Environment, University of Queensland, QLD, Australia.
The transition to net zero emissions requires the capture of carbon dioxide from industrial point sources, and direct air capture (DAC) from the atmosphere for geological storage. Dissolved CO has reactivity to rock core, and while the majority of previous studies have concentrated on reservoir rock or cap-rock reactivity, the underlying seal formation may also react with CO. Drill core from the underlying seal of a target CO storage site was reacted at in situ conditions with pure CO, and compared with an impure CO stream with SO, NO and O that could be expected from hard to abate industries.
View Article and Find Full Text PDFEnergy Fuels
January 2025
Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99354, United States.
The Co-Optimization of Fuels and Engines (Co-Optima) is a research and development consortia funded by the U.S. Department of Energy, which has engaged partners from national laboratories, universities, and industry to conduct multidisciplinary research at the intersection of biofuels and combustion sciences.
View Article and Find Full Text PDFBiological soil crusts (or biocrust) are diminutive soil communities with ecological functions disproportionate to their size. These communities are composed of lichens, bryophytes, cyanobacteria, fungi, liverworts, and other microorganisms. Creating stabilizing matrices, these microorganisms interact with soil surface minerals thereby enhancing soil quality by redistributing nutrients and reducing erosion by containment of soil particles.
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