We show unequivocal evidence for formation of He_{2}^{*} excimers in liquid He II created by ionizing radiation produced through neutron capture. Laser beams induce fluorescence of the excimers. The fluorescence is recorded at a rate of 55.6 Hz by a camera. The location of the fluorescence is determined with an uncertainty of 5 μm. The technique provides an opportunity to record the flow of He_{2}^{*} excimers in a medium with very small viscosity and enables measurement of turbulence around macroscopic liter size objects or vortex matter in three dimensions.
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http://dx.doi.org/10.1103/PhysRevLett.124.134502 | DOI Listing |
Phys Rev Lett
April 2020
Department of Physics and Astronomy, University of Tennessee, Knoxville, Tennessee 37996, USA.
We show unequivocal evidence for formation of He_{2}^{*} excimers in liquid He II created by ionizing radiation produced through neutron capture. Laser beams induce fluorescence of the excimers. The fluorescence is recorded at a rate of 55.
View Article and Find Full Text PDFRev Sci Instrum
March 2020
Institute for Integrated Radiation and Nuclear Science, Kyoto University, Kumatori, Osaka 590-0494, Japan.
For the purpose of future visualization of the flow field in superfluid helium-4, clusters of the triplet state excimer He are generated along the micro-scale recoil tracks of the neutron-absorption reaction n + He → T + p. This reaction is induced by neutron irradiation of the He fraction contained in natural isotopic abundance liquid helium with neutron beams either from the Japan Proton Accelerator Research Complex, Materials and Life Science Experimental Facility (JPARC)/Materials and Life Science Experimental Facility or from the Kyoto University Institute for Integrated Radiation and Nuclear Science. These He clusters are expected to be ideal tracers of the normal-fluid component in superfluid helium with several advantageous properties.
View Article and Find Full Text PDFJ Chem Theory Comput
October 2018
Kenneth S. Pitzer Center for Theoretical Chemistry, Department of Chemistry , University of California at Berkeley, Berkeley , California 94720 , United States.
We present an improved energy decomposition analysis (EDA) scheme for understanding intermolecular interactions in delocalized excited states, especially in excimers. In the EDA procedure, excited states are treated with linear response theory such as configuration interaction singles (CIS) or time-dependent density functional theory (TDDFT), and absolutely localized molecular orbitals (ALMOs) are used to define the intermediate (frozen, excitonic coupling, and polarized) states. The intermolecular interaction energy is thereby separated into frozen, excitonic splitting, polarization, and charge transfer contributions.
View Article and Find Full Text PDFJ Chem Phys
April 2018
Laboratoire Collisions Agrégats Réactivité (LCAR), IRSAMC, Université de Toulouse, CNRS UMR 5589, Toulouse, France.
The possibility for helium-induced electronic transitions in a photo-excited atom is investigated using Ba excited to the 6p P state as a prototypical example. A diabatization scheme has been designed to obtain the necessary potential energy surfaces and couplings for complexes of Ba with an arbitrary number of helium atoms. It involves computing new He-Ba electronic wave functions and expanding them in determinants of the non-interacting complex.
View Article and Find Full Text PDFJ Comput Chem
May 2017
Departamento de Física y Química Teórica, Facultad de Química, UNAM, México City, 04510, México.
This work provides a novel interpretation of elementary processes of photophysical relevance from the standpoint of the electron density using simple model reactions. These include excited states of H taken as a prototype for a covalent bond, excimer formation of He to analyze non-covalent interactions, charge transfer by an avoided crossing of electronic states in LiF and conical interesections involved in the intramolecular scrambling in C H . The changes of the atomic and interaction energy components along the potential energy profiles are described by the interacting quantum atoms approach and the quantum theory of atoms in molecules.
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